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The effect of heat-treating a typical activated carbon at 1600-2500 degreesC on its structural and textural properties was investigated by gas sorption and X-ray diffraction. Particular attention was paid to the recovery of the surface area and porosity of thermally treated carbons by means of oxidation treatments. It was found that the thermal modification of activated carbon could eliminate carbon impurities, bring about different degrees of graphitization, and improve the resistance of the carbon support to undergo methanation under ammonia synthesis conditions, but the surface area and porosity decreased dramatically. Oxidative treatment partially recovered the surface area and porosity. The higher the thermal treatment temperature, the greater the stability of the carbon support, and the more difficult the recovery of the surface area and porosity becomes. A series of unpromoted ruthenium/carbon catalysts showed that the highly developed texture of the carbon support resulted in a significant increase in Ru dispersion. The ammonia synthesis activity of a Ba-promoted Ru catalyst was greatly improved by using activated carbon C1900ox as a support, which was heated at 1900 degreesC in an inert atmosphere and then subjected to oxidation treatment. (C) 2002 Elsevier Science Ltd. All rights reserved.
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CARBON
ISSN: 0008-6223
Year: 2002
Issue: 14
Volume: 40
Page: 2597-2603
3 . 0 4 8
JCR@2002
1 0 . 5 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 93
SCOPUS Cited Count: 102
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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