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author:

HUANG, JL (HUANG, JL.) [1] | LIU, SX (LIU, SX.) [2] | HUANG, BQ (HUANG, BQ.) [3]

Indexed by:

SCIE

Abstract:

The two title compounds obtained by solid state reaction at high temperature were characterized as isomorphism by single-crystal X-ray diffraction. The space group of both crystals is C2-nu-4-Pma2, with lattice constants a = 7.955(1), b = 6.258 (1), c = 7.203(2) angstrom for I, and a = 7.914 (1), b = 6.237 (1), c = 7.236 (1) angstrom for II, Z = 2. The structures were determined by normal method and refined to the final R = 0.074 and 0.083, respectively. The results show that the structure may be regarded as building by cluster unit with formula Ni2M2Te4 (M = Nb or Ta) in which two Ni atoms and two M atoms form a rhombus, while the Te atoms are distorted tetrahedrally coordinated with both kinds of metal atoms. In the cluster unit there exist interactions between Ni atoms as well as between Ni and M atoms. In addition, all the cluster units are linked together not only by bridging Te atoms, but also by weaker metal-metal interactions, so as to form two-dimensional network. Therefore, the structure may be represented by the formula [Ni2M2(mu-4-Te)6/3 (mu-4-Te)4/2]infinity. A preliminary measurement of electric conductivity shows that the crystals of the two title compounds are metallic but their conductivities are anisotropic; those parallel to the a-b axes are about 10(3)OMEGA-1 . cm-1, whereas those along the c axis are about 10-OMEGA-1 . cm-1.

Keyword:

CRYSTAL STRUCTURE METAL CLUSTERS SOLID STATE CHEMISTRY TELLURIDES

Community:

  • [ 1 ] ACAD SINICA,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA

Reprint 's Address:

  • 黄金陵

    [HUANG, JL]FUZHOU UNIV,CTR RES SOLID STATE MAT,FUZHOU 350002,PEOPLES R CHINA

Email:

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Source :

SCIENCE IN CHINA SERIES B-CHEMISTRY LIFE SCIENCES & EARTH SCIENCES

ISSN: 1001-652X

Year: 1991

Issue: 6

Volume: 34

Page: 666-674

0 . 4 7 9

JCR@1998

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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