• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Wang, Ruo (Wang, Ruo.) [1] | Zhang, Tesen (Zhang, Tesen.) [2] | Zhang, Qianru (Zhang, Qianru.) [3] | Zheng, Mingwen (Zheng, Mingwen.) [4] | Xu, Kai (Xu, Kai.) [5] | Yan, Weitao (Yan, Weitao.) [6]

Indexed by:

EI

Abstract:

With the development of the times, the energy density of cathodes can no longer meet the requirement of the society, which has greatly limited the commercialization process of Ni-rich cathodes. Doping combined with coating is a perfect approach to improve the performance of Ni-rich cathodes. In this paper, La was used as a modified element to realize doping in the layered host structure as well as La2O3 coating on the surface. To further enhance the interface stability of LiNi0.8Co0.1Mn0.1O2, F was also employed to modify the surface, so as to change the coating layer from oxide (La2O3) to fluoride (LaF3), which further improved the surface stability. Additionally, a series of testing instruments, including XRD, EDS mapping, and HRTEM, were employed, which suggested that a small amount of La was introduced into the host structure as a pillar to the stable layered structure, and there was an uniform LaF3 coating layer covered on the Ni-rich cathodes. As a result, the electrochemical performance of the cathodes was greatly improved, with the capacity retention of 86.63% and 80.79% after 200 cycles at 1 C rate and 300 cycles at 8 C rate, respectively; besides, the kinetics of lithium diffusion was also improved. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.

Keyword:

Cathodes Coatings Doping (additives) Fluorine compounds Instrument testing Lanthanum Lanthanum oxides Nickel compounds Nickel metallography

Community:

  • [ 1 ] [Wang, Ruo]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Zhang, Tesen]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 3 ] [Zhang, Qianru]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 4 ] [Zheng, Mingwen]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 5 ] [Xu, Kai]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 6 ] [Yan, Weitao]College of Chemistry, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • [wang, ruo]college of chemistry, fuzhou university, fuzhou; 350116, china

Show more details

Related Keywords:

Source :

Ionics

ISSN: 0947-7047

Year: 2020

Issue: 3

Volume: 26

Page: 1165-1171

2 . 8 1 7

JCR@2020

2 . 4 0 0

JCR@2023

ESI HC Threshold:115

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:234/10041161
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1