Persistent radical anions in panchromatic D-A hybrid heterostructures induced by anion-π interactions - Details

author：

You, Ming-Hua (You, Ming-Hua.) ^[1] | Di, Yi-Ming (Di, Yi-Ming.) ^[2] | Li, Meng-Hua (Li, Meng-Hua.) ^[3] | Li, Hao-Hong (Li, Hao-Hong.) ^[4] | Lin, Mei-Jin (Lin, Mei-Jin.) ^[5]

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Abstract：

The　combination　of　N,　N′-dipyridyl-tetrachloroperylene　diimide　(4Cl-DPPDI)　buliding　blocks　with　lead　iodides　in　the　presence　of　hydrogen　iodides　led　to　a　novel　D-A　hybrid　heterostructure　with　segregated　iodoplumbate　anions　and　2-D　H-bonded　4Cl-DPPDI　networks　as　electron　donors　and　acceptors.　Due　to　the　compact　anion-π　interactions　as　well　as　small　energy　gaps　between　the　donors　and　acceptors,　persistent　and　stable　radical　anions　are　generated　in　such　a　unique　complex　triggered　by　natural-light　irradiation,　which　thus　exhibits　a　panchromatic　absorption.　©　2020　Elsevier　Ltd

Keyword：

Lead compounds Negative ions

Community：

[ 1 ] [You, Ming-Hua]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, 350116, China
[ 2 ] [You, Ming-Hua]College of Zhicheng, Fuzhou University, 350002, China
[ 3 ] [Di, Yi-Ming]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, 350116, China
[ 4 ] [Li, Meng-Hua]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, 350116, China
[ 5 ] [Li, Hao-Hong]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, 350116, China
[ 6 ] [Lin, Mei-Jin]Key Laboratory of Molecule Synthesis and Function Discovery, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, 350116, China

Reprint 's Address：

[lin, mei-jin]key laboratory of molecule synthesis and function discovery, state key laboratory of photocatalysis on energy and environment, college of chemistry, fuzhou university, 350116, china

Email：

meijin_lin@fzu.edu.cn

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Source ：

Dyes and Pigments

ISSN： 0143-7208

Year： 2020

Volume： 180

4 . 8 8 9

JCR@2020

4 . 1 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：1

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 8

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 0

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