Heterobimetallic　zeolites　have　been　considered　as　highly　efficient　catalysts　to　reduce　nitrogen　oxide　emissions,　but　economic　and　sustainable　preparation　methods　have　been　lacking.　This　paper　presents　an　economic　and　sustainable　one-pot　synthesis　strategy　to　prepare　the　heterobimetallic　FeCu-SSZ-13　zeolite　(FeCu-SSZ-13M)　with　high　crystallinity　via　the　mesoscale　depolymerization-reorganization　of　natural　aluminosilicate　minerals　without　the　use　of　any　synthetic　silicon-,　aluminum-,　and　iron-containing　chemicals.　Systematic　characterization　results　reveal　that　the　resultant　FeCu-SSZ-13M　sample　has　smaller　crystallize　size,　larger　specific　surface　area　and　pore　volume　(especially　external　specific　surface　area　and　mesopore　volume),　lower　acid　strength　and　more　isolated　Cu2+　and　framework　Fe3+　ions　when　compared　with　Cu-SSZ-13C　and　FeCu-SSZ-13C　prepared　from　conventional　precursors.　Therefore,　it　exhibits　outstanding　catalytic　performance　(such　as　super-wide　reaction　temperature　window,　excellent　hydrothermal　stability,　high　H2O　and　SO2　tolerance,　and　good　gaseous　hourly　space　velocity　flexibility)　in　the　selective　catalytic　reduction　of　NO　by　NH3.　Our　research　contributes　to　the　design　and　synthesis　of　an　efficient　environmental　protection　catalyst　in　an　economic　and　sustainable　manner.　©　2020　Elsevier　B.V.