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author:

Wang, Qian (Wang, Qian.) [1] | Chen, Mingming (Chen, Mingming.) [2] | Zhang, Jiaxin (Zhang, Jiaxin.) [3] | Yu, Ting (Yu, Ting.) [4] | Fu, FengFu (Fu, FengFu.) [5] | Dong, Yongqiang (Dong, Yongqiang.) [6]

Indexed by:

EI

Abstract:

Carbon based dots capped tin oxide nanosheets (SnO2/CDs) were synthesized by liquid exfoliation of tin oxide (SnO2) nanoparticles in the presence of single-layer carbon based (CDs). The obtained SnO2/CDs have lateral sizes of about 20–50 nm and heights of about 3–4 nm. A thin layer of CDs of about 1–2 nm in thickness are presence on the surface of the SnO2 nanosheets. The SnO2/CDs present excellent surface enhanced Raman spectroscopy (SERS) activity due to the chemical enhancement (CM) led by the charge transfer between SnO2/CDs and the target molecules. The enhancement factor (EF) of the SnO2/CDs is 1.42 × 105, taking rhodamine 6G as a model target molecule. The SnO2/CDs are further hybridized with silver nanoparticles (AgNPs) using an in situ synthesis method. The obtained homogeneous nano-hybrids (SnO2/CDs@AgNPs) have a lot of nanogaps. The nanogaps among the AgNPs/CDs create strong electromagnetic enhancement (EM) due to the 'hot spots' effect. The nanogaps among the SnO2/CDs and AgNPs/CDs allow the target molecules to be embedded, and thus gained both the CM effect of SnO2/CDs and the EM effect of AgNPs/CDs. As a result, the as-prepared SnO2/CDs@AgNPs exhibits excellent SERS activities, with an ultrahigh enhancement factor of 3.27 × 1011. © 2020 Elsevier Ltd

Keyword:

Charge transfer Metal nanoparticles Molecules Nanosheets Raman scattering Raman spectroscopy Silver nanoparticles Substrates Surface scattering Synthesis (chemical) Tin oxides

Community:

  • [ 1 ] [Wang, Qian]MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 2 ] [Wang, Qian]Division of Physics and Applied Physics School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore
  • [ 3 ] [Chen, Mingming]MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 4 ] [Zhang, Jiaxin]MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 5 ] [Yu, Ting]Division of Physics and Applied Physics School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore
  • [ 6 ] [Fu, FengFu]MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 7 ] [Dong, Yongqiang]MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, China

Reprint 's Address:

  • [yu, ting]division of physics and applied physics school of physical and mathematical sciences, nanyang technological university, 637371, singapore

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Source :

Carbon

ISSN: 0008-6223

Year: 2020

Volume: 170

Page: 270-276

9 . 5 9 4

JCR@2020

1 0 . 5 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 11

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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