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author:

He, Suqiong (He, Suqiong.) [1] | Wu, Chuxin (Wu, Chuxin.) [2] | Sun, Zhen (Sun, Zhen.) [3] | Liu, Yang (Liu, Yang.) [4] | Hu, Rongtao (Hu, Rongtao.) [5] | Guan, Lunhui (Guan, Lunhui.) [6] | Zhan, Hongbing (Zhan, Hongbing.) [7]

Indexed by:

EI

Abstract:

In order to promote the commercial application of proton exchange membrane fuel cells, it is of great importance to develop Pt-based electrocatalysts with high activity and stability for the oxygen reduction reaction (ORR). Here, urchin-like mesoporous TiO2 hollow spheres (UMTHS) with a high specific surface area (167.1 m2 g-1) and improved conductivity were designed and applied as supports to disperse Pt nanoparticles (NPs) for the first time. Uniform Pt NPs (∼3.2 nm) on the surface of nanothorns were obtained after heat treatment. The as-prepared product (Pt/UMTHS) exhibited a more positive half-wave potential (Eh) than that of the reference sample Pt@C without UMTHS (0.867 V vs. 0.829 V). The improved performance can be ascribed to the high specific surface area of UMTHS. The Pt/UMTHS also exhibited a much better ORR stability than the commercial Pt/C after long-term cycling at 0.6-1.0 V according to the comparison of Eh, mass activity and electrochemical surface area with Pt/C. The enhanced stability of Pt/UMTHS was mainly derived from the strong metal support interaction between Pt NPs and UMTHS, together with the spatial restriction and the anti-restriction provided by UMTHS. © 2020 The Royal Society of Chemistry.

Keyword:

After-heat treatment Electrocatalysts Electrolytic reduction Metal nanoparticles Oxide minerals Oxygen Oxygen reduction reaction Platinum Proton exchange membrane fuel cells (PEMFC) Specific surface area TiO2 nanoparticles Titanium dioxide

Community:

  • [ 1 ] [He, Suqiong]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 2 ] [He, Suqiong]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350116, China
  • [ 3 ] [Wu, Chuxin]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350116, China
  • [ 4 ] [Sun, Zhen]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 5 ] [Sun, Zhen]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350116, China
  • [ 6 ] [Liu, Yang]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350116, China
  • [ 7 ] [Hu, Rongtao]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350116, China
  • [ 8 ] [Guan, Lunhui]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350116, China
  • [ 9 ] [Zhan, Hongbing]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China

Reprint 's Address:

  • [zhan, hongbing]college of materials science and engineering, fuzhou university, fuzhou, fujian; 350108, china

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Source :

Nanoscale

ISSN: 2040-3364

Year: 2020

Issue: 19

Volume: 12

Page: 10656-10663

7 . 7 9

JCR@2020

5 . 8 0 0

JCR@2023

ESI HC Threshold:115

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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