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author:

Luo, Yu (Luo, Yu.) [1] | Shi, Yixiang (Shi, Yixiang.) [2] | Chen, Yanbo (Chen, Yanbo.) [3] | Li, Wenying (Li, Wenying.) [4] | Jiang, Lilong (Jiang, Lilong.) [5] | Cai, Ningsheng (Cai, Ningsheng.) [6]

Indexed by:

EI

Abstract:

To improve the energy-to-CH4 efficiency and enhance renewable power utilization, we investigate direct Power-to-Methane at low inlet H2 content (25 vol%) in solid oxide electrolysis cell (SOEC). The synergy of the pressurized operation and the electricity input effectively enhances CH4 yield by one-order of magnitude from 2.8% to 28.7% and the CO2-to-CH4 ratio from 4.4% to 39.5% in the H2-reduced case, where the ratio of H2 consumption to total energy consumption decreases to 41% and the energy-to-CH4 efficiency increases to 53%. We develop a multiphysics tubular SOEC model to understand the intrinsic coupling between electrochemistry and heterogeneous catalytic chemistry. From the perspective of performance enhancement, geometry optimization, and thermal design, inhibiting CH4 production in the inlet gas-controlled zone and promoting CH4 production synergistically in both the electrochemistry-controlled zone and the temperature-controlled zone is the key to improve the energy-to-CH4 efficiency. © 2019 American Institute of Chemical Engineers

Keyword:

Energy efficiency Energy utilization Gas industry Methane Regenerative fuel cells Solid oxide fuel cells (SOFC)

Community:

  • [ 1 ] [Luo, Yu]Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Energy and Power Engineering, Tsinghua University, Beijing, China
  • [ 2 ] [Luo, Yu]National Engineering Research Center for Chemical Fertilizer Catalyst (NERC-CFC), School of Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 3 ] [Shi, Yixiang]Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Energy and Power Engineering, Tsinghua University, Beijing, China
  • [ 4 ] [Chen, Yanbo]Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Energy and Power Engineering, Tsinghua University, Beijing, China
  • [ 5 ] [Li, Wenying]Sichuan Energy Internet Research Institute, Tsinghua University, Sichuan, China
  • [ 6 ] [Jiang, Lilong]National Engineering Research Center for Chemical Fertilizer Catalyst (NERC-CFC), School of Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 7 ] [Cai, Ningsheng]Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Energy and Power Engineering, Tsinghua University, Beijing, China

Reprint 's Address:

  • [shi, yixiang]key laboratory for thermal science and power engineering of ministry of education, department of energy and power engineering, tsinghua university, beijing, china

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Source :

AIChE Journal

ISSN: 0001-1541

Year: 2020

Issue: 5

Volume: 66

3 . 9 9 3

JCR@2020

3 . 5 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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