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author:

Wang, Junmei (Wang, Junmei.) [1] | Xu, Qinchao (Xu, Qinchao.) [2] | Liu, Manli (Liu, Manli.) [3] | Wang, Kefeng (Wang, Kefeng.) [4] | Wang, Zhijian (Wang, Zhijian.) [5] | Qu, Peng (Qu, Peng.) [6]

Indexed by:

EI

Abstract:

Earth-abundant transition metal cocatalysts are promising rare and noble metal alternatives for efficient photocatalytic hydrogen evolution. Herein, a novel composite of ZIF-67 derived CoOx nanodots confined in a N, S co-doped graphitic nanosheet co-catalyst (CoOx@N, S-C) was successfully constructed via a one pot carbonization process. Through loading onto photosensitizer of CdS nanorods, the obtained CoOx@N, S-C/CdS composite exhibited an unprecedented H2 production rate of 40.1 mmol g-1 h-1, which is 57, 20 and 1.7 times higher than that of CdS, N, S-C/CdS and CoOx/CdS, respectively. It was demonstrated that the excellent photocatalytic H2 production performance arises from the synergetic effect between the confined ultrafine CoOx nanodots and N, S heteroatom co-doped graphitic carbon. This work shows considerable improvements over MOF derived materials as non-noble cocatalysts and provides significant motivation for new photocatalyst development for improving the conversion efficiency of solar energy to chemical fuels. © 2020 The Royal Society of Chemistry.

Keyword:

Cadmium sulfide Carbon Carbonization Cobalt compounds Hydrogen production II-VI semiconductors Nanocatalysts Nanodots Nanorods Photosensitizers Precious metals Solar energy

Community:

  • [ 1 ] [Wang, Junmei]Henan Engineering Center of New Energy Battery Materials, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu; 476000, China
  • [ 2 ] [Wang, Junmei]College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou; 450001, China
  • [ 3 ] [Xu, Qinchao]State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan; 030001, China
  • [ 4 ] [Liu, Manli]College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou; 450001, China
  • [ 5 ] [Wang, Kefeng]Henan Engineering Center of New Energy Battery Materials, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu; 476000, China
  • [ 6 ] [Wang, Zhijian]State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan; 030001, China
  • [ 7 ] [Wang, Zhijian]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou; 350116, China
  • [ 8 ] [Qu, Peng]Henan Engineering Center of New Energy Battery Materials, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu; 476000, China

Reprint 's Address:

  • [wang, zhijian]state key laboratory of photocatalysis on energy and environment, fuzhou university, fuzhou; 350116, china;;[wang, zhijian]state key laboratory of coal conversion, institute of coal chemistry, chinese academy of sciences, taiyuan; 030001, china

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Source :

Sustainable Energy and Fuels

Year: 2020

Issue: 4

Volume: 4

Page: 1954-1962

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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