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author:

Wang, Bingqing (Wang, Bingqing.) [1] | Ding, Yao (Ding, Yao.) [2] | Deng, Zirong (Deng, Zirong.) [3] | Li, Zhaohui (Li, Zhaohui.) [4]

Indexed by:

EI PKU CSCD

Abstract:

The NiS/CQDs nanocomposite (CQDs represents carbon quantum dots), with a mass ratio of NiS/CQDs to be 1.19:1 based on the ICP result, was obtained via a facile hydrothermal method from a mixture of CQDs, Ni(OAc)2 and Na2S. The self-assembly of ZnIn2S4 microspheres on the surface of NiS/CQDs was realized under microwave conditions to obtain a ternary NiS/CQDs/ZnIn2S4 nanocomposite. The as-obtained NiS/CQDs/ZnIn2S4 nanocomposite was fully characterized, and its photocatalytic hydrogen evolution under visible light irradiation was investigated. The ternary NiS/CQDs/ZnIn2S4 nanocomposite showed superior photocatalytic activity for hydrogen evolution than ternary CQDs/NiS/ZnIn2S4, which was obtained by deposition of NiS in the preformed CQDs/ZnIn2S4. The superior photocatalytic performance of ternary NiS/CQDs/ZnIn2S4 is ascribed to the introduction of CQDs, which act as a bridge to promote the vectorial transfer of photo-generated electrons from ZnIn2S4 to NiS. This result suggests that the rational design and fabrication of ternary CQDs-based systems are important for the efficient photocatalytic hydrogen evolution. This study provides a strategy for developing highly efficient noble-metal-free photocatalysts for hydrogen evolution using CQDs as a bridge to promote the charge transfer in the nanocomposite. © 2019 Dalian Institute of Chemical Physics, the Chinese Academy of Sciences

Keyword:

Carbon Quantum Dots Charge transfer Hydrogen Indium compounds Light Nanocomposites Nanocrystals Nickel Nickel sulfates Photocatalysis Photocatalytic activity Precious metals Semiconductor quantum dots Sodium sulfide Zinc compounds

Community:

  • [ 1 ] [Wang, Bingqing]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 2 ] [Ding, Yao]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 3 ] [Deng, Zirong]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 4 ] [Li, Zhaohui]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350116, China

Reprint 's Address:

  • [li, zhaohui]research institute of photocatalysis, state key laboratory of photocatalysis on energy and environment, college of chemistry, fuzhou university, fuzhou; fujian; 350116, china

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Source :

Chinese Journal of Catalysis

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2019

Issue: 3

Volume: 40

Page: 335-342

6 . 1 4 6

JCR@2019

1 5 . 7 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 99

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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