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author:

Cui, Qingyan (Cui, Qingyan.) [1] (Scholars:崔勍焱) | Zhang, Haobin (Zhang, Haobin.) [2] | Wei, Qiang (Wei, Qiang.) [3] | Yue, Yuanyuan (Yue, Yuanyuan.) [4] (Scholars:岳源源) | Wang, Tinghai (Wang, Tinghai.) [5] (Scholars:王廷海) | Zhu, Haibo (Zhu, Haibo.) [6] (Scholars:朱海波) | Zhou, Yasong (Zhou, Yasong.) [7] | Bao, Xianjun (Bao, Xianjun.) [8]

Indexed by:

EI PKU CSCD

Abstract:

Y zeolite was modified with Zr by equal volume impregnation method. The effects of different amounts of Zr on the structure of modified Y zeolite, the physicochemical properties of the catalyst and the performance of hydrocracking reaction were investigated systematically. The modified Y zeolite and catalyst were characterized by X-ray diffraction (XRD), NH3 temperature programmed desorption (NH3-TPD), H2 temperature programmed reduction (H2-TPR) and transmission electron microscopy (TEM). The results show that Zr modification decreased the amount of acid sites of Y zeolite, and the trend became larger with an increase of Zr content. Moreover, Zr modification availably weakened the relation of metal species and support in the catalyst with Y zeolite, and improved the dispersion of W species on the catalyst surface. The hydrocracking reaction results suggested that VGO conversion over the catalyst with Y zeolite modified with Zr decreased compared with that with Y zeolite, and middle distillates increased about 20%(mass), as well as VGO conversion gradually decreased and the middle distillates slightly increased as the Zr content increased. © All Right Reserved.

Keyword:

Ammonia Catalysts Catalyst supports High resolution transmission electron microscopy Hydrocracking Physicochemical properties Supports Surface reactions Temperature programmed desorption Zeolites Zirconium

Community:

  • [ 1 ] [Cui, Qingyan]College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 2 ] [Cui, Qingyan]State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing; 102249, China
  • [ 3 ] [Zhang, Haobin]College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 4 ] [Wei, Qiang]State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing; 102249, China
  • [ 5 ] [Yue, Yuanyuan]College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 6 ] [Wang, Tinghai]College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 7 ] [Zhu, Haibo]College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 8 ] [Zhou, Yasong]State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing; 102249, China
  • [ 9 ] [Bao, Xianjun]College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China

Reprint 's Address:

  • [zhou, yasong]state key laboratory of heavy oil processing, china university of petroleum, beijing; 102249, china

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Source :

CIESC Journal

ISSN: 0438-1157

CN: 11-1946/TQ

Year: 2019

Issue: 10

Volume: 70

Page: 3949-3955

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

Online/Total:187/10000283
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