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author:

Yang, Sen (Yang, Sen.) [1] | Chen, Xing (Chen, Xing.) [2] | Mi, Zhen-Zhen (Mi, Zhen-Zhen.) [3] | Chen, Zhi-Min (Chen, Zhi-Min.) [4] | Li, Xiao-Dong (Li, Xiao-Dong.) [5] | Sun, Jian-Jun (Sun, Jian-Jun.) [6] | Wu, Shao-Hua (Wu, Shao-Hua.) [7]

Indexed by:

EI

Abstract:

Electrically heated electrodes have been applied for various chemical and biological sensors. However, previous electrically heated electrodes, including microwires and microdiscs, are usually small and often suffer from the requirement of frequent calibrations of the electrode surface temperature (Ts) at different environment temperatures. Here, we fabricate a temperature-controllable disk electrode (TCDE) with a conventional size (3-5 mm in diameter). A one-parameter temperature calibration is proposed using a temperature transfer coefficient α and a structural model (Ts = Te + α (Th - Te)) to estimate Ts (Th and Te are the temperature of the heating element and environment, respectively). The value of α is unique for a TCDE and mainly dependent on the structure and materials of the electrodes and the solution in nature. Once α is experimentally determined, Ts can be calibrated and found to be applicable to wide fluctuations in room temperature (15.0-33.0 °C) with errors below 1.5% for three types of disk electrodes (gold, glassy carbon, and platinum). The required Ts can be obtained by just setting Th without thermal characterization between the heating power and Ts. A simple relationship for exploring the dependence of α on the height (H) and radius (R) of the electrode materials and other constants (a, b, c, and R0), α = 1 - c - aH - b (R - R0)2, is revealed by numerical simulations (COMSOL). The impact of the radii of both the insulating materials of the electrode and the electrochemical cells on Ts is also considered. The effect of the solution thermal conductivity on α is studied. TCDEs are expected to be used as a sensor platform with enhanced performance. © 2019 American Chemical Society.

Keyword:

Atmospheric temperature Calibration Computer simulation Electrochemical electrodes Heat transfer Numerical models Surface properties Temperature control Thermal conductivity

Community:

  • [ 1 ] [Yang, Sen]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 2 ] [Chen, Xing]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 3 ] [Mi, Zhen-Zhen]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 4 ] [Chen, Zhi-Min]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 5 ] [Li, Xiao-Dong]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 6 ] [Sun, Jian-Jun]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 7 ] [Wu, Shao-Hua]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian; 350108, China

Reprint 's Address:

  • [sun, jian-jun]ministry of education key laboratory for analytical science of food safety and biology, fujian provincial key laboratory of analysis and detection technology for food safety, college of chemistry, fuzhou university, fuzhou, fujian; 350108, china

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Source :

ACS Sensors

Year: 2019

Issue: 6

Volume: 4

Page: 1594-1602

7 . 3 3 3

JCR@2019

8 . 3 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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