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author:

Lin, Guoliang (Lin, Guoliang.) [1] | Li, Dongwei (Li, Dongwei.) [2] | Liu, Minyi (Liu, Minyi.) [3] | Zhang, Xiaoyi (Zhang, Xiaoyi.) [4] | Zheng, Yuying (Zheng, Yuying.) [5]

Indexed by:

EI

Abstract:

Poly(ethylene terephthalate) (PET) composites containing carbon fiber (CF) or polymethyl methacrylate (PMMA)-grafted carbon fiber (PMMA-g-CF) were prepared by melt compounding. The rheology, non-isothermal crystallization behavior, and mechanical and thermal properties of pure PET, PET/CF and PET/PMMA-g-CF composites were investigated. The results show that the addition of CF or PMMA-g-CF significantly increases the storage modulus (G'), loss modulus (G''), and complex viscosity (η*) of the composites at low frequency. The Cole-Cole plots confirm that the surface modification of CF leads to a better interaction between the CF and PET, and then decreases the heterogeneity of the polymeric systems, which is confirmed by the SEM observation on the tensile fracture surface of the composites. Non-isothermal crystallization analysis shows that the CF or PMMA-g-CF could serve as nucleation agent to accelerate the crystallization rate of the composites, and the effect of PMMA-g-CF is stronger than that of CF. The result is further confirmed by the analysis of the crystallization activation energy for all composites calculated by the Flynn-Wall-Ozawa method. Moreover, the tensile and impact strength and the thermal stability of the composites are improved by CF, while the incorporation of PMMA-g-CF further enhances the tensile and impact strength and thermal stability. © 2018 by the authors.

Keyword:

Activation analysis Activation energy Aliphatic compounds Carbon fibers Crystallization Elasticity Ethylene Fibers Impact strength Isotherms Polyethylene terephthalates Polymethyl methacrylates Rheology Tensile strength Thermodynamic properties Thermodynamic stability

Community:

  • [ 1 ] [Lin, Guoliang]Fujian Provincial Key Laboratory of Advanced Technology and Informatization in Civil Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 2 ] [Lin, Guoliang]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 3 ] [Li, Dongwei]Fujian Provincial Key Laboratory of Advanced Technology and Informatization in Civil Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 4 ] [Liu, Minyi]College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou; 350118, China
  • [ 5 ] [Zhang, Xiaoyi]Fujian Provincial Key Laboratory of Advanced Technology and Informatization in Civil Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 6 ] [Zheng, Yuying]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • [zheng, yuying]college of chemistry and chemical engineering, fuzhou university, fuzhou; 350116, china

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Related Keywords:

Source :

Polymers

Year: 2018

Issue: 6

Volume: 10

3 . 1 6 4

JCR@2018

4 . 7 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:150/10041981
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