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author:

Wang, Qun (Wang, Qun.) [1] | Huang, Jianying (Huang, Jianying.) [2] | Sun, Hongtao (Sun, Hongtao.) [3] | Ng, Yun Hau (Ng, Yun Hau.) [4] | Zhang, Ke-Qin (Zhang, Ke-Qin.) [5] | Lai, Yuekun (Lai, Yuekun.) [6]

Indexed by:

EI

Abstract:

TiO2 nanotube arrays (TiO2 NTAs) decorated with molybdenum disulfide quantum dots (MoS2 QDs) were synthesized by a facile electrodeposition method and used as a composite photocatalyst. MoS2 QDs/TiO2 NTAs showed enhanced photocatalytic activity compared with pristine TiO2 NTAs for solar light-promoted H2 evolution without adding any sacrificial agents or cocatalysts. The photocatalytic activity was influenced by the amount of MoS2 QDs coated on TiO2 NTAs. The optimal composition showed excellent photocatalytic activity, achieving H2 evolution rates of 31.36, 5.29, and 1.67 μmol cm−2 h−1 corresponding to ultraviolet (UV, λ760) illumination, respectively. The improved photocatalytic activity was attributed to the decreased bandgap and the surface plasmonic properties of MoS2 QDs/TiO2 NTAs, which promoted electron–hole pair separation and the absorption capacity for Vis and NIR light. This study presents a facile approach for fabricating MoS2 QDs/TiO2 NTA heterostructures for efficient photocatalytic H2 evolution, which will facilitate the development of designing new photocatalysts for environment and energy applications. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keyword:

Binary alloys Graphene quantum dots Infrared devices Layered semiconductors Molybdenum compounds Nanocrystals Nanotubes Oxide minerals Photocatalytic activity Semiconductor quantum dots Solar power generation Sulfur compounds Surface plasmons Titanium dioxide Titanium oxides Uranium alloys Vanadium alloys

Community:

  • [ 1 ] [Wang, Qun]College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou; 215123, China
  • [ 2 ] [Wang, Qun]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou; 215123, China
  • [ 3 ] [Huang, Jianying]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou; 215123, China
  • [ 4 ] [Huang, Jianying]College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 5 ] [Sun, Hongtao]College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou; 215123, China
  • [ 6 ] [Ng, Yun Hau]Particles and Catalysis Research Group, School of Chemical Engineering, University of New South Wales, High Street, Kensington; NSW; 2052, Australia
  • [ 7 ] [Zhang, Ke-Qin]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou; 215123, China
  • [ 8 ] [Lai, Yuekun]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou; 215123, China
  • [ 9 ] [Lai, Yuekun]College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • [lai, yuekun]college of chemical engineering, fuzhou university, fuzhou; 350116, china;;[lai, yuekun]national engineering laboratory for modern silk, college of textile and clothing engineering, soochow university, suzhou; 215123, china

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Source :

ChemSusChem

ISSN: 1864-5631

Year: 2018

Issue: 10

Volume: 11

Page: 1708-1721

7 . 8 0 4

JCR@2018

7 . 5 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 80

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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