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author:

Fu, Bin-Bin (Fu, Bin-Bin.) [1] | Zheng, Yu-Ying (Zheng, Yu-Ying.) [2] (Scholars:郑玉婴) | Chen, Jian (Chen, Jian.) [3] | Zou, Hai-Qiang (Zou, Hai-Qiang.) [4] | Zheng, Wei-Jie (Zheng, Wei-Jie.) [5] | Chen, Xue-Hong (Chen, Xue-Hong.) [6]

Indexed by:

EI PKU CSCD

Abstract:

A series of Mn-Ce-Co-Ox/PPS composite filter materials with different mass ratios were obtained by modifying the pristine polyphenylene sulfide (PPS) filter material with sodium dodecyl sulfate (SDS) and then treated by a redox precipitation method. The Mn-Ce-Co-Ox/PPS composite filter materials were characterized by XRD, FESEM, TEM and XPS; their catalytic performance in the low-temperature selective catalytic reduction (SCR) of NOx was then investigated. The results show that the Mn-Ce-Co-Ox/PPS composite filter materials obtained by the redox method presents higher low-temperature SCR activity than the Mn-Ce-Co-Ox/PPS-UM composite filter material fabricated via the ultrasonic method; over the former material, the NOx conversion reaches 86%-100% at 120-160. Among them, the 1.2Mn-Ce-Co-Ox/PPS composite filter material displays the highest SCR activity, which is probably ascribed to the high Ce3+/(Ce3++Ce4+) ratio and high concentration of Co; moreover, honeycomb-like MnO2, Ce2O3, CeO2, CoO and Co3O4 are uniformly distributed on the PPS filter material in the weak crystalline structure. In comparison with Mn-Ce-Co-Ox/PPS-UM, the 1.2Mn-Ce-Co-Ox/PPS composite filter material also exhibits higher resistance to H2O and SO2. © 2017, Science Press. All right reserved.

Keyword:

Cerium oxide Cobalt compounds Denitrification Manganese oxide Nitrogen oxides Nitrogen removal Precipitation (chemical) Selective catalytic reduction Sodium dodecyl sulfate Sulfur compounds Temperature

Community:

  • [ 1 ] [Fu, Bin-Bin]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Zheng, Yu-Ying]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Chen, Jian]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Zou, Hai-Qiang]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Zheng, Wei-Jie]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 6 ] [Chen, Xue-Hong]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China

Reprint 's Address:

  • 郑玉婴

    [zheng, yu-ying]college of materials science and engineering, fuzhou university, fuzhou; 350108, china

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Source :

Journal of Fuel Chemistry and Technology

ISSN: 0253-2409

Year: 2017

Issue: 6

Volume: 45

Page: 731-739

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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