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Abstract:
A series of Mn-Ce-Co-Ox/PPS composite filter materials with different mass ratios were obtained by modifying the pristine polyphenylene sulfide (PPS) filter material with sodium dodecyl sulfate (SDS) and then treated by a redox precipitation method. The Mn-Ce-Co-Ox/PPS composite filter materials were characterized by XRD, FESEM, TEM and XPS; their catalytic performance in the low-temperature selective catalytic reduction (SCR) of NOx was then investigated. The results show that the Mn-Ce-Co-Ox/PPS composite filter materials obtained by the redox method presents higher low-temperature SCR activity than the Mn-Ce-Co-Ox/PPS-UM composite filter material fabricated via the ultrasonic method; over the former material, the NOx conversion reaches 86%-100% at 120-160. Among them, the 1.2Mn-Ce-Co-Ox/PPS composite filter material displays the highest SCR activity, which is probably ascribed to the high Ce3+/(Ce3++Ce4+) ratio and high concentration of Co; moreover, honeycomb-like MnO2, Ce2O3, CeO2, CoO and Co3O4 are uniformly distributed on the PPS filter material in the weak crystalline structure. In comparison with Mn-Ce-Co-Ox/PPS-UM, the 1.2Mn-Ce-Co-Ox/PPS composite filter material also exhibits higher resistance to H2O and SO2. © 2017, Science Press. All right reserved.
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Journal of Fuel Chemistry and Technology
ISSN: 0253-2409
Year: 2017
Issue: 6
Volume: 45
Page: 731-739
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 5
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