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author:

Long, Bo (Long, Bo.) [1] | Cheng, Shuying (Cheng, Shuying.) [2] | Zheng, Qiao (Zheng, Qiao.) [3] | Yu, Jinling (Yu, Jinling.) [4] | Jia, Hongjie (Jia, Hongjie.) [5]

Indexed by:

EI

Abstract:

Cu2ZnSnS4 (CZTS) thin films have been successfully deposited by a sol-gel method and sulfurization process. The properties of the films were investigated by varying sulfurization time and H2S concentration. X-ray diffraction and Raman spectra analyses revealed the formation of CZTS films with a tetragonal type kesterite structure. With increasing the sulfurization time and H2S concentration, the intensity of the kesterite (1 1 2) peak became sharper. The stoichiometric ratios of the CZTS films were different from the precursors, which was due to Sn loss during the sulfurization process. The electrical resistivity and mobility of the films increased while the carrier concentration decreased with increasing the sulfurization time. The CZTS thin films sulfurized at 5% H2S concentration for 90 min had the best opto-electrical properties with Eg of 1.41 eV, resistivity of 3.64 Ω cm, carrier concentration of 1.11 × 1018 cm-3 and mobility of 1.54 cm2/(V s) at room temperature for PV application.

Keyword:

Carrier concentration Carrier mobility Copper compounds Optical properties Sol-gel process Sol-gels Thin films Tin compounds Zinc compounds

Community:

  • [ 1 ] [Long, Bo]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Cheng, Shuying]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Cheng, Shuying]Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou, 213164, China
  • [ 4 ] [Zheng, Qiao]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Zheng, Qiao]Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou, 213164, China
  • [ 6 ] [Yu, Jinling]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou; 350108, China
  • [ 7 ] [Yu, Jinling]Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou, 213164, China
  • [ 8 ] [Jia, Hongjie]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou; 350108, China
  • [ 9 ] [Jia, Hongjie]Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou, 213164, China

Reprint 's Address:

  • [cheng, shuying]jiangsu collaborative innovation center of photovolatic science and engineering, changzhou, 213164, china;;[cheng, shuying]college of physics and information engineering, institute of micro-nano devices and solar cells, fuzhou university, fuzhou; 350108, china

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Source :

Materials Research Bulletin

ISSN: 0025-5408

Year: 2016

Volume: 73

Page: 140-144

2 . 4 4 6

JCR@2016

5 . 3 0 0

JCR@2023

ESI HC Threshold:324

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 24

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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