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author:

Lin, Jiuyang (Lin, Jiuyang.) [1] | Ye, Wenyuan (Ye, Wenyuan.) [2] | Baltaru, Marian-Cornel (Baltaru, Marian-Cornel.) [3] | Tang, Yu Pan (Tang, Yu Pan.) [4] | Bernstein, Nicole J. (Bernstein, Nicole J..) [5] | Gao, Peng (Gao, Peng.) [6] | Balta, Stefan (Balta, Stefan.) [7] | Vlad, Maria (Vlad, Maria.) [8] | Volodin, Alexander (Volodin, Alexander.) [9] | Sotto, Arcadio (Sotto, Arcadio.) [10] | Luis, Patricia (Luis, Patricia.) [11] | Zydney, Andrew L. (Zydney, Andrew L..) [12] | Van der Bruggen, Bart (Van der Bruggen, Bart.) [13]

Indexed by:

EI

Abstract:

Nanofiltration (NF) membranes have been used previously for the recovery of dyes, salts, and water from textile wastewaters with high salinity. However, commercially available NF membranes have a high rejection for divalent salts (i.e., Na2SO4), substantially reducing the salt recovery and membrane flux when treating textile wastewater containing Na2SO4. In this study, a tight ultrafiltration membrane (UH004, Microdyn-Nadir) was proposed to fractionate the dye and Na2SO4 in the textile wastewater. The UH004 membrane with a molecular weight cutoff of 4700 Da provided complete passage of monovalent salts, with little rejection of Na2SO4. This significantly increases the filtrate flux that can be achieved with high-salinity wastewater since osmotic pressure and concentration polarization effects are minimized. Furthermore, the retention behavior of four different dyes was evaluated to determine the efficiency of this membrane process. This tight ultrafiltration membrane offered the high retention for direct dyes (i.e., direct red 80, direct red 23, and Congo red) and reactive blue 2. For instance, the UH004 membrane yielded >98.9% rejection for all of the dyes at a pressure of 4 bar even in the presence of 60 g L-1 Na2SO4. Subsequently, an ultrafiltration-diafiltration process was designed to separate a dye/Na2SO4 aqueous mixture with 98% desalination efficiency and greater than 97% dye recovery after 5 diavolumes. These results clearly demonstrate that tight ultrafiltration membranes can be a stand-alone alternative to NF membranes for the effective fractionation of dye and Na2SO4 in the direct treatment of high-salinity textile wastewater. © 2016 Elsevier B.V.

Keyword:

Azo dyes Desalination Efficiency Fractionation Membranes Osmosis Recovery Salts Sodium sulfate Textiles Ultrafiltration Wastewater treatment Water filtration

Community:

  • [ 1 ] [Lin, Jiuyang]School of Environment and Resources, Fuzhou University, Qi Shan Campus, No.2 Xueyuan Road, University Town, Fuzhou, Fujian; 350116, China
  • [ 2 ] [Ye, Wenyuan]Department of Chemical Engineering, KU Leuven, Willem de Croylaan 46, Heverlee; B-3001, Belgium
  • [ 3 ] [Baltaru, Marian-Cornel]Department of Environmental and Material Engineering, Dunarea de Jos University, Galati; 800201, Romania
  • [ 4 ] [Tang, Yu Pan]Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineerings Drive 4, Singapore; 117576, Singapore
  • [ 5 ] [Bernstein, Nicole J.]Department of Chemical Engineering, Fenske Laboratory, Pennsylvania State University, University Park; PA; 16802, United States
  • [ 6 ] [Gao, Peng]School of Municipal and Environmental Engineering, Harbin Institute of Technology, No. 73 Huanghe Road, Nangang District, Harbin; 150090, China
  • [ 7 ] [Balta, Stefan]Department of Environmental and Material Engineering, Dunarea de Jos University, Galati; 800201, Romania
  • [ 8 ] [Vlad, Maria]Department of Environmental and Material Engineering, Dunarea de Jos University, Galati; 800201, Romania
  • [ 9 ] [Volodin, Alexander]Laboratory of Solid-State Physics and Magnetism, Department of Physics and Astronomy, KU Leuven, Celestijnenlaan 200D, Leuven; B-3001, Belgium
  • [ 10 ] [Sotto, Arcadio]Department of Chemical and Environmental Technology, Rey Juan Carlos University, Móstoles, Madrid; 28933, Spain
  • [ 11 ] [Luis, Patricia]Materials and Process Engineering (iMMC-IMAP), Université catholique de Louvain, Louvain-la-Neuve; 1348, Belgium
  • [ 12 ] [Zydney, Andrew L.]Department of Chemical Engineering, The Pennsylvania State University, University Park; PA; 16802, United States
  • [ 13 ] [Van der Bruggen, Bart]Department of Chemical Engineering, KU Leuven, Willem de Croylaan 46, Heverlee; B-3001, Belgium

Reprint 's Address:

  • [ye, wenyuan]department of chemical engineering, ku leuven, willem de croylaan 46, heverlee; b-3001, belgium

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Source :

Journal of Membrane Science

ISSN: 0376-7388

Year: 2016

Volume: 514

Page: 217-228

6 . 0 3 5

JCR@2016

8 . 4 0 0

JCR@2023

ESI HC Threshold:235

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 362

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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