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author:

Chen, Xin (Chen, Xin.) [1] | Gong, Zhongliang (Gong, Zhongliang.) [2] | Wan, Qiping (Wan, Qiping.) [3] | Wu, Shuting (Wu, Shuting.) [4] | Guo, Feiyun (Guo, Feiyun.) [5] | Zhuang, Naifeng (Zhuang, Naifeng.) [6] | Chen, Jianzhong (Chen, Jianzhong.) [7]

Indexed by:

EI

Abstract:

Ba3Tb(PO4)3 crystals have been grown by the slow-cooling method and the Czochralski technique for the first time for magneto-optical applications. The single-crystal X-ray diffraction confirms that the compound crystallizes in the cubic system I4¯3d, with eulytite structure with a = 10.4484(12) Å, V = 1140.6(2) Å3 and Z = 4. The hardness of Ba3Tb(PO4)3 crystal is about 5.5 Moh. The temperature dependence of the magnetic susceptibility indicated that the Ba3Tb(PO4)3 crystal exhibits paramagnetic behavior over the experimental temperature-range 2-300 K. Transmittance spectra and the Faraday rotation have been investigated, which demonstrate that Ba3Tb(PO4)3 crystal shows a higher visible transparency than Tb3Ga5O12 crystal and yields a Faraday rotation comparable to that of Sr3Tb(BO3)3 crystal. Ba3Tb(PO4)3 is therefore a promising material in particular for new magneto-optical applications in the visible region. © 2015 Elsevier B.V. All rights reserved.

Keyword:

Barium compounds Crystal growth Crystal structure Faraday effect Gallium compounds Magnetic susceptibility Magnetism Optical properties Phosphates Single crystals Strontium compounds Temperature distribution Terbium compounds

Community:

  • [ 1 ] [Chen, Xin]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Gong, Zhongliang]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Wan, Qiping]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Wu, Shuting]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Guo, Feiyun]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 6 ] [Zhuang, Naifeng]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 7 ] [Chen, Jianzhong]College of Chemistry, Fuzhou University, Fuzhou; 350108, China

Reprint 's Address:

  • [chen, jianzhong]college of chemistry, fuzhou university, fuzhou; 350108, china

Email:

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Source :

Optical Materials

ISSN: 0925-3467

Year: 2015

Issue: 1

Volume: 44

Page: 48-53

2 . 1 8 3

JCR@2015

3 . 8 0 0

JCR@2023

ESI HC Threshold:335

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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