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author:

Fang, Lihua (Fang, Lihua.) [1] | Zhang, Qi (Zhang, Qi.) [2] | Lin, Fen (Lin, Fen.) [3] | Tang, Dian (Tang, Dian.) [4] | Zhang, Teng (Zhang, Teng.) [5]

Indexed by:

EI

Abstract:

The insufficient thermal-mechanical stability of sealing interface presents a challenge for the development of solid oxide fuel cells (SOFCs). Here we report for the first time that the presence of gadolinia-doped ceria (GDC) electrolyte leads to the formation of two hardystonite phases, (Ca0.9Zn0.03)2(Al0.63Zn0.37)(Si0.69Al0.31)2O7 and Ca2ZnSi2O7, in the reaction couples between boroaluminosilicate sealing glass-ceramics and GDC powders held at 700°C for 30 days. Similarly, the aggregation of these two hardystonite phases also occurs at the interface between GDC and sealing glass-ceramics under identical heat-treatment. In particular, (Ca0.9Zn0.03)2(Al0.63Zn0.37)(Si0.69Al0.31)2O7 becomes the dominant phase at the sealing interface when the heat-treatment time increases from 7 days to 30 days. Moreover, the sealing interface remains intact after thermal cycles for 100 times, indicating the excellent thermal-mechanical stability of hardystonite phases. Finally, the possible mechanism on the phase evolution of glass-ceramic at the sealing interface has been proposed. © 2015 Elsevier Ltd.

Keyword:

Cerium oxide Glass ceramics Heat treatment Mechanical stability Solid electrolytes Solid oxide fuel cells (SOFC)

Community:

  • [ 1 ] [Fang, Lihua]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 2 ] [Zhang, Qi]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 3 ] [Lin, Fen]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 4 ] [Tang, Dian]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China
  • [ 5 ] [Zhang, Teng]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian; 350108, China

Reprint 's Address:

  • [zhang, teng]college of materials science and engineering, fuzhou university, fuzhou, fujian; 350108, china

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Source :

Journal of the European Ceramic Society

ISSN: 0955-2219

Year: 2015

Issue: 7

Volume: 35

Page: 2201-2207

2 . 9 3 3

JCR@2015

5 . 8 0 0

JCR@2023

ESI HC Threshold:335

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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