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Abstract:
The insufficient thermal-mechanical stability of sealing interface presents a challenge for the development of solid oxide fuel cells (SOFCs). Here we report for the first time that the presence of gadolinia-doped ceria (GDC) electrolyte leads to the formation of two hardystonite phases, (Ca0.9Zn0.03)2(Al0.63Zn0.37)(Si0.69Al0.31)2O7 and Ca2ZnSi2O7, in the reaction couples between boroaluminosilicate sealing glass-ceramics and GDC powders held at 700°C for 30 days. Similarly, the aggregation of these two hardystonite phases also occurs at the interface between GDC and sealing glass-ceramics under identical heat-treatment. In particular, (Ca0.9Zn0.03)2(Al0.63Zn0.37)(Si0.69Al0.31)2O7 becomes the dominant phase at the sealing interface when the heat-treatment time increases from 7 days to 30 days. Moreover, the sealing interface remains intact after thermal cycles for 100 times, indicating the excellent thermal-mechanical stability of hardystonite phases. Finally, the possible mechanism on the phase evolution of glass-ceramic at the sealing interface has been proposed. © 2015 Elsevier Ltd.
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Journal of the European Ceramic Society
ISSN: 0955-2219
Year: 2015
Issue: 7
Volume: 35
Page: 2201-2207
2 . 9 3 3
JCR@2015
5 . 8 0 0
JCR@2023
ESI HC Threshold:335
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
SCOPUS Cited Count: 10
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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