Syntheses, structure and magnetic properties of two vanadate garnets Ca5M4V6O24 (M=Co, Ni) - Details

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Abstract：

Two　vanadate　compounds　Ca5M4V6O24　(M=Co,　Ni)　have　been　synthesized　by　a　higherature　solid-state　reaction.　The　compounds　are　found　to　crystallize　in　the　cubic　system　with　a　space　group　Ia-3d,　which　exhibit　a　typical　garnet　structural　framework.　Magnetic　measurements　show　that　Ca5M4V6O24　(M=Co,　Ni)　exhibit　similar　magnetic　behaviors,　in　which　Ca5Co4V6O24　possesses　an　antiferromagnetic　ordering　at　TN=~6　K　while　Ca5Ni4V6O24　shows　an　antiferromagnetic　ordering　at　TN=~7　K.　©　2015　Elsevier　Inc.　All　rights　reserved.

Keyword：

Antiferromagnetism Calcium compounds Cobalt compounds Crystal structure Garnets Magnetic properties Nickel compounds Solid state reactions Vanadium compounds

Community：

[ 1 ] [Wang, Nannan]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 2 ] [Wang, Nannan]College of Materials Science and Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
[ 3 ] [He, Zhangzhen]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 4 ] [He, Zhangzhen]Key Laboratory of Optoelectronic Materials Chemistry and PhysicsFujian, Institute of Research on the Structure of MatterChinese Academy of Sciences, Fuzhou; 350002, China
[ 5 ] [Cui, Meiyan]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 6 ] [Guo, Wenbin]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 7 ] [Zhang, Suyun]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 8 ] [Yang, Ming]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 9 ] [Tang, Yingying]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China

Reprint 's Address：

[he, zhangzhen]key laboratory of optoelectronic materials chemistry and physicsfujian, institute of research on the structure of matterchinese academy of sciences, fuzhou; 350002, china;;[he, zhangzhen]state key laboratory of structural chemistry, fujian institute of research on the structure of matter, chinese academy of sciences, fuzhou; 350002, china

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Source ：

Journal of Solid State Chemistry

ISSN： 0022-4596

Year： 2015

Volume： 228

Page： 245-249

2 . 2 6 5

JCR@2015

3 . 2 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：2

CAS Journal Grade：3

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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