Five　Nd-contained　POM　complexes　doped　with　transition　metal　were　synthesized　by　adopting　mild　aqueous　method　(TM=Mn(1),　Co(2),　Ni(3),　Cu(4),　Zn(5)).　The　structures　of　complexes　were　characterized　by　X-ray　powder　diffraction,　and　the　presence　of　transition　metal　was　confirmed　by　inductively　coupled　plasma　optical　emission　spectrometry　and　solid-state　UV-Vis　diffraction　spectrometry.　The　influence　of　transition　metal　dopant　on　multi-color　properties,　fluorescence,　and　magnetism　were　discussed　as　well.　It　was　found　that　the　complexes　with　dopant　showed　distinct　tinctorial　effect,　and　various　multi-color　effect.