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author:

Liu, J.R. (Liu, J.R..) [1] | Hong, R.Y. (Hong, R.Y..) [2] | Feng, W.G. (Feng, W.G..) [3] | Badami, D. (Badami, D..) [4] | Wang, Y.Q. (Wang, Y.Q..) [5]

Indexed by:

EI

Abstract:

Large-scale production of strontium hexaferrite (SrFe12O19) particles was successfully achieved by molten-salt-assisted coprecipitation. A mixture of sodium hydroxide and sodium carbonate was served as mixed precipitant to obtain ferrite precursors. The effects of the Fe3+/Sr2+ molar ratio, calcination temperature, calcination time, and molten-salt amount on the formation, morphology and magnetic properties of SrFe12O19 particles were investigated. The resultant particles were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, and vibrating sample magnetometer. Single-phase SrFe12O19 particles, with particle sizes of 0.8-1.2μm, were obtained from the precursor (with a Fe3+/Sr2+ molar ratio of 10) being calcined at 950°C for 2h using the mass ratio (NaCl to precursor) of 0.3. The saturation magnetization, remanent magnetization and coercivity were about 62emu/g, 37emu/g, and 4310Oe, respectively. A comparison of the products obtained at different preparation-scales was also done. The results showed that it was easier to control the particle morphology using molten salt synthesis and more economical on a large-scale production. © 2014 Elsevier B.V.

Keyword:

Calcination Coprecipitation Ferrite Fourier transform infrared spectroscopy Fused salts Iron compounds Magnetic properties Molar ratio Morphology Particle size analysis Saturation magnetization Scanning electron microscopy Sodium Carbonate Sodium chloride Sodium hydroxide Strontium Strontium compounds Thermogravimetric analysis

Community:

  • [ 1 ] [Liu, J.R.]School of Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Hong, R.Y.]School of Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Hong, R.Y.]College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123, China
  • [ 4 ] [Feng, W.G.]Suzhou Nanocomp Inc., Suzhou New District, Suzhou 215011, China
  • [ 5 ] [Badami, D.]Department of Chemical Engineering, University of Waterloo, Ontario, N2L3G1, Canada
  • [ 6 ] [Wang, Y.Q.]College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Reprint 's Address:

  • [hong, r.y.]school of chemical engineering, fuzhou university, fuzhou 350108, china;;[hong, r.y.]college of chemistry, chemical engineering and materials science, key laboratory of organic synthesis of jiangsu province, soochow university, suzhou 215123, china

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Source :

Powder Technology

ISSN: 0032-5910

Year: 2014

Volume: 262

Page: 142-149

2 . 3 4 9

JCR@2014

4 . 5 0 0

JCR@2023

ESI HC Threshold:268

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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