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Abstract:
The modified starch was prepared through the soluble starch wet graft vinyl acetate and the environmental friendly EVA sole foaming materials were obtained with the modified starch. The effect and structure of the modified starch was analyzed by FT-IR, grafting ratio and grafting efficiency, while the mechanical properties and microscopic morphology of the modified starch/EVA sole foaming materials were also investigated. According to the results, the FT-IR spectrum of the modified starch showed a adsorption peak at 1746 cm-1, which was assigned to the stretching vibration of the carbonyl group and indicated that the monomer of vinyl acetate might graft onto the bone of the starch. The best initiator concentration was 7 mmol/L and the optimum reaction temperature was 70°C. The SEM pictures demonstrated that the modified starch and EVA had good compatibility. The proportion of wet grafted starch/EVA sole foaming materials were lower than traditional EVA sole foaming materials, when the content of the grafted starch was 40 phr, the proportion of the composite foaming materials reached the minimum, which was 0.085 g/cm3.
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Journal of Functional Materials
ISSN: 1001-9731
CN: 50-1099/TH
Year: 2013
Issue: 15
Volume: 44
Page: 2253-2257
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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