An air-stable copper reagent for nucleophilic trifluoromethylthiolation of aryl halides - Details

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Abstract：

A　series　of　copper(I)　trifluoromethyl　thiolate　complexes　have　been　synthesized　from　the　reaction　of　CuF2　with　Me3SiCF　3　and　S8　(see　scheme;　Cu　red,　F　green,　N　blue,　S　yellow).　These　air-stable　complexes　serve　as　reagents　for　the　efficient　conversion　of　a　wide　range　of　aryl　halides　into　the　corresponding　aryl　trifluoromethyl　thioethers　in　excellent　yields.　Copyright　©　2013　WILEY-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim.

Keyword：

Chemical bonds Copper Copper compounds Fluorine compounds Metal halides Silicon compounds Synthesis (chemical)

Community：

[ 1 ] [Weng, Zhiqiang]Department of Chemistry, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
[ 2 ] [He, Weiming]Department of Chemistry, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Chen, Chaohuang]Department of Chemistry, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
[ 4 ] [Lee, Richmond]Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
[ 5 ] [Tan, Davin]Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
[ 6 ] [Lai, Zhiping]Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
[ 7 ] [Kong, Dedao]Department of Chemistry, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
[ 8 ] [Yuan, Yaofeng]Department of Chemistry, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
[ 9 ] [Huang, Kuo-Wei]Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

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Email：

zweng@fzu.edu.cn

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Source ：

Angewandte Chemie - International Edition

ISSN： 1433-7851

Year： 2013

Issue： 5

Volume： 52

Page： 1548-1552

1 1 . 3 3 6

JCR@2013

1 6 . 1 0 0

JCR@2023

JCR Journal Grade：1

CAS Journal Grade：1

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WoS CC Cited Count：

SCOPUS Cited Count： 269

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 0

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