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author:

Kailasam, Kamalakannan (Kailasam, Kamalakannan.) [1] | Schmidt, Johannes (Schmidt, Johannes.) [2] | Bildirir, Hakan (Bildirir, Hakan.) [3] | Zhang, Guigang (Zhang, Guigang.) [4] | Blechert, Siegfried (Blechert, Siegfried.) [5] | Wang, Xinchen (Wang, Xinchen.) [6] | Thomas, Arne (Thomas, Arne.) [7]

Indexed by:

EI

Abstract:

Two emerging material classes are combined in this work, namely polymeric carbon nitrides and microporous polymer networks. The former, polymeric carbon nitrides, are composed of amine-bridged heptazine moieties and showed interesting performance as a metal-free photocatalyst. These materials have, however, to be prepared at high temperatures, making control of their chemical structure difficult. The latter, microporous polymer networks have received increasing interest due to their high surface area, giving rise to interesting applications in gas storage or catalysis. Here, the central building block of carbon nitrides, a functionalized heptazine as monomer, and tecton are used to create microporous polymer networks. The resulting heptazine-based microporous polymers show high porosity, while their chemical structure resembles the ones of carbon nitrides. The polymers show activity for the photocatalytic production of hydrogen from water, even under visible light illumination. Heptazine-based microporous polymer networks (HMPs) are synthesized by room temperature polycondensation of cyameluric chloride with aromatic diamines. Polymer networks with significant surface area and pore volume are obtained. HMPs are active and stable photocatalysts for the production of hydrogen from water, even under visible light irradiation. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keyword:

Aromatic polymers Carbon nitride Chlorine compounds Conjugated polymers Hydrogen production Light Microporosity Nitrides Photocatalytic activity Structure (composition)

Community:

  • [ 1 ] [Kailasam, Kamalakannan]Technische Universität Berlin, Department of Chemistry/Functional Materials, Hardenbergstr. 40, 10623 Berlin, Germany
  • [ 2 ] [Schmidt, Johannes]Technische Universität Berlin, Department of Chemistry/Functional Materials, Hardenbergstr. 40, 10623 Berlin, Germany
  • [ 3 ] [Bildirir, Hakan]Technische Universität Berlin, Department of Chemistry/Functional Materials, Hardenbergstr. 40, 10623 Berlin, Germany
  • [ 4 ] [Zhang, Guigang]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, College of Chemistry and Chemical Engineering, Fuzhou University, 350002 Fuzhou, China
  • [ 5 ] [Blechert, Siegfried]Technische Universität Berlin, Department of Chemistry/Organic Chemistry, Str. des 17. Juni 135, 10623 Berlin, Germany
  • [ 6 ] [Wang, Xinchen]Fujian Provincial Key Laboratory of Photocatalysis-State Key Laboratory Breeding Base, College of Chemistry and Chemical Engineering, Fuzhou University, 350002 Fuzhou, China
  • [ 7 ] [Thomas, Arne]Technische Universität Berlin, Department of Chemistry/Functional Materials, Hardenbergstr. 40, 10623 Berlin, Germany

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Source :

Macromolecular Rapid Communications

ISSN: 1022-1336

Year: 2013

Issue: 12

Volume: 34

Page: 1008-1013

4 . 6 0 8

JCR@2013

4 . 2 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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