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author:

Li, Nan (Li, Nan.) [1] | Fang, Qinmei (Fang, Qinmei.) [2] | Yan, Xiaobo (Yan, Xiaobo.) [3] | Zheng, Kuicheng (Zheng, Kuicheng.) [4] | Lin, Guangmei (Lin, Guangmei.) [5] | Fu, Wusheng (Fu, Wusheng.) [6]

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EI Scopus PKU CSCD

Abstract:

The fatty acid esters of chloropropanols (referred to as chloropropanols) in edible vegetable oil is a new food pollutant of international concern recently and its pollution is investigated firstly in this paper. Eleven kinds of edible vegetable oils, such as soybean oil, camellia oil and peanut oil, were sampled in the numerous chain supermarkets in China and divided into 143 parts. After alkaline hydrolysis, the oil samples were purified with matrix solid-phase dispersion (MSPD) of kieselguhr. The extract was derived and then detected by gas chromatography with mass spectrometry (GC/MS). 3-chloropropane-1, 2-diol (3-MCPD ester) and 2-chloropropane-1, 3-diol ester (2-MCPD ester) were determined quantitatively with stability isotope internal standard method and were found detectable rate of 74.8%, 49.7% in 11 kinds of edible vegetable oils, respectively. The contents ranged from <limit of detection (LOD) (0.064 mg/kg) to 5.96 mg/kg (calculated as dissociated 3-MCPD) and < LOD (0.072 mg/kg) to 3.43 mg/kg (calculated as dissociated 2-MCPD), respectively. Relatively serious pollution problems were found in camellia oil and sesame oil, and the median was 1.63 mg/kg and 0.60 mg/kg, respectively. There was a linear correlation between the contents of 3-MCPD ester and 2-MCPD ester with the correlation coefficient of 0.899.

Keyword:

Chemical contamination Esterification Esters Fatty acids Gas chromatography Isotopes Mass spectrometry Matrix solid phase dispersion Pollution Surveys Vegetable oils

Community:

  • [ 1 ] [Li, Nan]Fujian Provincial Key Laboratory of Zoonosis, Fujian Center for Disease Control and Prevention, Fuzhou 350001, China
  • [ 2 ] [Li, Nan]College of Food Science and Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China
  • [ 3 ] [Fang, Qinmei]Biotechnology Research Institute, Fujian Academy of Agricultural Sciences, Fuzhou 350003, China
  • [ 4 ] [Yan, Xiaobo]Fujian Provincial Key Laboratory of Zoonosis, Fujian Center for Disease Control and Prevention, Fuzhou 350001, China
  • [ 5 ] [Yan, Xiaobo]Key Laboratory of Analysis and Detection for Food Safety of Ministry Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 6 ] [Zheng, Kuicheng]Fujian Provincial Key Laboratory of Zoonosis, Fujian Center for Disease Control and Prevention, Fuzhou 350001, China
  • [ 7 ] [Lin, Guangmei]College of Food Science and Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China
  • [ 8 ] [Fu, Wusheng]Fujian Provincial Key Laboratory of Zoonosis, Fujian Center for Disease Control and Prevention, Fuzhou 350001, China
  • [ 9 ] [Fu, Wusheng]Key Laboratory of Analysis and Detection for Food Safety of Ministry Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 10 ] [Fu, Wusheng]Teaching Base of Fujian Medical University in Fujian Center for Disease Control and Prevention, Fuzhou 350001, China

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Source :

Journal of the Chinese Cereals and Oils Association

ISSN: 1003-0174

CN: 11-2864/TS

Year: 2013

Issue: 8

Volume: 28

Page: 28-32,36

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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