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Abstract:
The fatty acid esters of chloropropanols (referred to as chloropropanols) in edible vegetable oil is a new food pollutant of international concern recently and its pollution is investigated firstly in this paper. Eleven kinds of edible vegetable oils, such as soybean oil, camellia oil and peanut oil, were sampled in the numerous chain supermarkets in China and divided into 143 parts. After alkaline hydrolysis, the oil samples were purified with matrix solid-phase dispersion (MSPD) of kieselguhr. The extract was derived and then detected by gas chromatography with mass spectrometry (GC/MS). 3-chloropropane-1, 2-diol (3-MCPD ester) and 2-chloropropane-1, 3-diol ester (2-MCPD ester) were determined quantitatively with stability isotope internal standard method and were found detectable rate of 74.8%, 49.7% in 11 kinds of edible vegetable oils, respectively. The contents ranged from <limit of detection (LOD) (0.064 mg/kg) to 5.96 mg/kg (calculated as dissociated 3-MCPD) and < LOD (0.072 mg/kg) to 3.43 mg/kg (calculated as dissociated 2-MCPD), respectively. Relatively serious pollution problems were found in camellia oil and sesame oil, and the median was 1.63 mg/kg and 0.60 mg/kg, respectively. There was a linear correlation between the contents of 3-MCPD ester and 2-MCPD ester with the correlation coefficient of 0.899.
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Journal of the Chinese Cereals and Oils Association
ISSN: 1003-0174
CN: 11-2864/TS
Year: 2013
Issue: 8
Volume: 28
Page: 28-32,36
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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