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author:

Cao, Jing (Cao, Jing.) [1] | Lü, Qiu-Feng (Lü, Qiu-Feng.) [2]

Indexed by:

EI

Abstract:

β-nucleated controlled-rheology polypropylene random copolymers (CRPPRs) were prepared by peroxide-initiated degradation via adding dicumyl peroxide (DCP) to β-nucleated PPR. Melt flow index (MFI) and mechanical properties of β-nucleated PPR and CRPPRs were analyzed and compared with PPR. Wide-angle X-ray diffractometer (WAXD), differential scanning calorimeter (DSC) and polarized light microscope (PLM) were used to study the crystalline structure and morphology. The results indicate that the MFI of β-nucleated CRPPR increases linearly with increasing DCP content. The strain hardening rate and impact strength of β-nucleated CRPPRs well reflect the degree of degradation and β-phase content. No significant change of yield strength and strain at break is seen with increasing DCP content, except for an increase of the latter when DCP content reaches 0.15 wt%. The maximum crystallinity is observed at 0.05 wt% DCP. β-nucleated CRPPRs show increased crystallization temperature and decreased β-crystal content and crystal size as DCP content increases. © 2011 Elsevier Ltd. All rights reserved.

Keyword:

Crystalline materials Crystallinity Differential scanning calorimetry Elasticity Impact strength Mechanical properties Morphology Oxidation Peroxides Polypropylenes Strain hardening Strain rate Structure (composition)

Community:

  • [ 1 ] [Cao, Jing]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, Fujian, China
  • [ 2 ] [Lü, Qiu-Feng]College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, Fujian, China

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Source :

Polymer Testing

ISSN: 0142-9418

Year: 2011

Issue: 8

Volume: 30

Page: 899-906

1 . 6 0 8

JCR@2011

5 . 0 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 39

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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