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author:

Zhang, Xing (Zhang, Xing.) [1] | Xuan, Zeliang (Xuan, Zeliang.) [2] | Cheng, Lei (Cheng, Lei.) [3] | Zheng, Yuying (Zheng, Yuying.) [4] (Scholars:郑玉婴)

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Abstract:

Mnodisperse micron-size polystyrene-butyl acrylate microspheres with smooth spherical surface were prepared by dispersion polymerization. The dependence of conversion-time on different parameters was studied; moreover, the kinetic equation of dispersion copolymerization was also obtained. The results show that when the monomer molar ratio BA/St is higher than 20/80 the total conversion decreases significantly, the total conversion increases with the temperature increasing from 60°C to 75 °C and decreases when 80 °C, the total conversion increases with the decrease of EtOH/H2O ratio and with the increase of initiator concentration. The dependence of total conversion on stabilizer concentration was not pronouncedly. The kinetic equation of the polymerization can be expressed as: Rp=k·exp(38194/RT) [St/BA]0.7029 [m(EtOH)/m(EtOH+H2O)]-4.138 [AIBN]0.3845(60 °C~75 °C). The overall activation energy for the rate of polymerization is 38.194 kJ/mol.

Keyword:

Activation energy Copolymerization Dispersions Ethanol Integral equations Kinetic energy Kinetics Kinetic theory Molar concentration Molar ratio Styrene

Community:

  • [ 1 ] [Zhang, Xing]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 2 ] [Xuan, Zeliang]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 3 ] [Cheng, Lei]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China
  • [ 4 ] [Zheng, Yuying]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

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Source :

Polymeric Materials Science and Engineering

ISSN: 1000-7555

CN: 51-1293/O6

Year: 2011

Issue: 4

Volume: 27

Page: 13-16,20

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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