Ordered　mesoporous　carbons　(OMCs)　with　well-developed　mesopores　were　synthesized　using　evaporation-induced　self-assembly　(EISA).　The　triblock　copolymer　P123/phenol-resin/silica　composites　were　prepared　by　EISA　using　tetraethyl　orthosilicate　as　the　inorganic　source,　P123　as　the　structure　directing　agent　and　phenol-resin　as　the　carbon　source.　OMCs　were　obtained　by　the　carbonization　of　the　composites,　followed　by　the　removal　of　the　silica　template　with　a　mass　fraction　10%　HF　aqueous　solution.　For　comparison,　another　OMC　was　synthesized　by　using　ordered　silica　as　a　hard　template　and　impregnated　sucrose　as　the　carbon　precursor.　The　samples　were　characterized　by　scanning　and　transmission　electron　microscopy　and　N2　sorption.　Results　indicated　that　the　OMCs　had　an　ordered　hexagonal　structure　with　a　narrow　distribution　of　mesopores.　The　optimized　OMC　was　obtained　using　a　P123/phenol-resin　mass　ratio　of　1:0.25.　Compared　with　the　OMCs　synthesized　by　the　hard　template　method,　the　new　OMCs　had　fewer　micro-　and　macropores.