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author:

Chen, Qingai (Chen, Qingai.) [1] | Zhou, Tingyao (Zhou, Tingyao.) [2] | He, Chunyan (He, Chunyan.) [3] | Jiang, Yaqi (Jiang, Yaqi.) [4] | Chen, Xi (Chen, Xi.) [5]

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EI

Abstract:

In this study, a rapid, convenient and in situ applicable Cu2+ sensor was constructed based on a luminescent layer immobilizing Ru (bpy) 3Cl2 with a maximum wavelength of 600 nm, which was taken as the reference background light. The luminescence intensity of the layer was kept constant and isolated from the oxygen change in the solution due to the hybrid polyacrylonitrile-dimethylsulfoxide used in the immobilization of the Ru(bpy)3Cl2. The CdTe quantum dot (QD) luminescence, with a maximum wavelength of 520 nm, was quenched to different degrees depending on the Cu 2+ concentration in the solution. Using a commercial camera, different colors could be captured in different Cu2+ concentrations. This color change was caused by the composite light with stable luminescence from the Ru (bpy)3Cl2 layer and the changeable fluorescence of the CdTe QDs. Sensor characteristics, including the co-existing ions, oxygen content, temperature effect, and sensor stability, were investigated. © 2011 The Royal Society of Chemistry.

Keyword:

Cadmium telluride Chlorine compounds Color Colorimetry II-VI semiconductors Light Luminescence Nanocrystals Oxygen Ruthenium Ruthenium compounds Semiconductor quantum dots

Community:

  • [ 1 ] [Chen, Qingai]College of Food Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, China
  • [ 2 ] [Zhou, Tingyao]State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen, 361005, China
  • [ 3 ] [He, Chunyan]Ministry of Education Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Jiang, Yaqi]Ministry of Education Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Chen, Xi]State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen, 361005, China

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Source :

Analytical Methods

ISSN: 1759-9660

Year: 2011

Issue: 7

Volume: 3

Page: 1471-1474

1 . 5 4 7

JCR@2011

2 . 7 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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