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author:

Lin, Zhi-Bin (Lin, Zhi-Bin.) [1] | Xie, Bu-Gao (Xie, Bu-Gao.) [2] | Tian, Jing-Hua (Tian, Jing-Hua.) [3] | Tang, Yong-An (Tang, Yong-An.) [4] | Sun, Jian-Jun (Sun, Jian-Jun.) [5] | Chen, Guo-Nan (Chen, Guo-Nan.) [6] | Ren, Bin (Ren, Bin.) [7] | Mao, Bing-Wei (Mao, Bing-Wei.) [8] | Tian, Zhong-Qun (Tian, Zhong-Qun.) [9]

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EI

Abstract:

The adsorption behavior of uracil, an excellent ligand in cyanide-free silver plating on silver electrodes was studied with potential-dependent surface-enhanced Raman spectroscopy (SERS). Uracil was adsorbed at the silver surface with N3-deprotonated tautomer at pH 10.2, while with N1- and N3-deprotonated tautomers at pH 13.6. Uracil and additive polyethyleneimine (PEI) exhibit a co-adsorption behavior that holds the same tendency as their adsorption on the silver surfaces alone. The effect of PEI on silver plating process is proposed from SERS and electrochemical analysis. PEI, acted as an efficient suppressor and grain refiner in this silver plating bath, was further confirmed by the AFM micrographs. © 2009 Elsevier B.V. All rights reserved.

Keyword:

Adsorption Alkalinity Aromatic compounds Electrodes Raman spectroscopy Silver Silver metallography Silver plating

Community:

  • [ 1 ] [Lin, Zhi-Bin]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Xie, Bu-Gao]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Tian, Jing-Hua]Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
  • [ 4 ] [Tang, Yong-An]Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
  • [ 5 ] [Sun, Jian-Jun]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Chen, Guo-Nan]MOE Key Laboratory of Analysis and Detection Technology for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 7 ] [Ren, Bin]Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
  • [ 8 ] [Mao, Bing-Wei]Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China
  • [ 9 ] [Tian, Zhong-Qun]Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China

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Source :

Journal of Electroanalytical Chemistry

ISSN: 1572-6657

Year: 2009

Issue: 1-2

Volume: 636

Page: 74-79

2 . 3 3 8

JCR@2009

4 . 1 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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