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Abstract:
The title complex, [Co(C15H12N3O2S)2], consists of an octa-hedrally coordinated CoII ion, with two crystallographically independent 1,4-dibenzoyl-thio-semicarbazidate ligands in a tridentate mer coordination [Co - O = 2.064 (3)-2.132 (3) A and Co - N = 2.037 (3)-2.043 (3) A]. There are inter-molecular N - HS hydrogen bonds involving one ligand and strong π - π stacking inter-actions involving the other ligand, resulting in a three-dimensional supra-molecular framework. The hydrogen bonds and π-π inter-actions, as well as different intra-molecular aryl-benzamide H - CH( - N) distances, give rise to a difference in conformation between the two ligands. © International Union of Crystallography 2007.
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Acta Crystallographica Section C: Crystal Structure Communications
ISSN: 0108-2701
Year: 2007
Issue: 8
Volume: 63
Page: m343-m345
0 . 7 1 9
JCR@2007
0 . 3 2 6
JCR@2014
JCR Journal Grade:3
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ESI Highly Cited Papers on the List: 0 Unfold All
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