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author:

Ke, Yuan-Zhen (Ke, Yuan-Zhen.) [1] | Zheng, Leng-Feng (Zheng, Leng-Feng.) [2] | Luo, Jian-Hai (Luo, Jian-Hai.) [3] | Huang, Xi-He (Huang, Xi-He.) [4] | Huang, Chang-Cang (Huang, Chang-Cang.) [5]

Indexed by:

EI

Abstract:

The title complex, [Co(C15H12N3O2S)2], consists of an octa-hedrally coordinated CoII ion, with two crystallographically independent 1,4-dibenzoyl-thio-semicarbazidate ligands in a tridentate mer coordination [Co - O = 2.064 (3)-2.132 (3) A and Co - N = 2.037 (3)-2.043 (3) A]. There are inter-molecular N - HS hydrogen bonds involving one ligand and strong π - π stacking inter-actions involving the other ligand, resulting in a three-dimensional supra-molecular framework. The hydrogen bonds and π-π inter-actions, as well as different intra-molecular aryl-benzamide H - CH( - N) distances, give rise to a difference in conformation between the two ligands. © International Union of Crystallography 2007.

Keyword:

Cobalt compounds Conformations Crystallography Hydrogen bonds Ligands

Community:

  • [ 1 ] [Ke, Yuan-Zhen]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 2 ] [Zheng, Leng-Feng]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 3 ] [Luo, Jian-Hai]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 4 ] [Huang, Xi-He]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 5 ] [Huang, Chang-Cang]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

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Source :

Acta Crystallographica Section C: Crystal Structure Communications

ISSN: 0108-2701

Year: 2007

Issue: 8

Volume: 63

Page: m343-m345

0 . 7 1 9

JCR@2007

0 . 3 2 6

JCR@2014

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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