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Using sodium carbonate as the catalyst, the carbon dioxide gasification kinetics of the four high rank anthracites (Vad = 2. 69% [similar to] 4. 35%) was investigated by isothermal thermo-gravimetric analysis under high pressure. The range of pressure from 0.101 MPa to 3.0 MPa was tested. The results show that when the pressure is higher than 2. 0 MPa, the increase of pressure has no effect on the reaction rate. The coal conversion as a function of reaction time was measured at the temperature from 750°C to 950°C and at 2. 0 MPa, which could be preferably correlated by the shrinking-core model (SCM). According to the reaction rate constant determined by SCM, the reactivity order of the four anthracites is: Yongan Fengshai coal > Yongan Jiashai coal > Yongding coal > Shangjing coal. The activation energies, ranging from 157. 21 kJ/mol to 185. 89 kJ/mol, are obtained. The reaction rate constant, activation energy and pre-exponential factor under high pressure are larger than those of the gasification in CO2 at atmospheric pressure. At 850°C the power of CO2 partial pressure for Yongan Jiashai coal is 0. 347 44, which agrees well with the literature.
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Journal of Fuel Chemistry and Technology
ISSN: 0253-2409
Year: 2006
Issue: 5
Volume: 34
Page: 530-535
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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