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author:

Zheng, Yundi (Zheng, Yundi.) [1] | Lin, Xingyi (Lin, Xingyi.) [2] | Zheng, Qi (Zheng, Qi.) [3] | Zhan, Yingying (Zhan, Yingying.) [4] | Li, Dalin (Li, Dalin.) [5] | Wei, Kemei (Wei, Kemei.) [6]

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EI

Abstract:

Cu/CeO2-ZrO2catalysts for water-gas shift (WGS) reaction were prepared with co-precipitation method, and the influence of ZrO2content on the catalytic structure and properties was investigated by the techniques of N2physical adsorption analysis, XRD and H2-TPR. The results indicate that the BET surface areas of the catalysts are increased in varying degrees due to the presence of ZrO2. With increasing ZrO2content, the pore size distribution is centered on 1.9 nm. ZrO2can efficiently restrain the growth of Cu crystal particles. The appropriate amount of ZrO2in the Cu/CeO2catalysts can help the catalyst keep better copper dispersion in the WGS reaction, which can lead to both higher catalytic activity and better thermal stability. When ZrO2content is 10% (atom fraction), Cu/CeO2-ZrO2catalyst reaches a CO conversion rate of 73.7% at the reaction temperature of 200°C.

Keyword:

Catalyst activity Catalysts Cerium compounds Coal gas Copper Performance Structure (composition) Thermodynamic stability Water Zirconia

Community:

  • [ 1 ] [Zheng, Yundi]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Lin, Xingyi]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Zheng, Qi]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Zhan, Yingying]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 5 ] [Li, Dalin]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [Wei, Kemei]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China

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Source :

Journal of Rare Earths

ISSN: 1002-0721

Year: 2005

Issue: 6

Volume: 23

Page: 685-689

0 . 2 4 9

JCR@2005

5 . 2 0 0

JCR@2023

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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