Hydrothermal synthesis and crystal structure of a novel 1D polyoxovanadium borate: (H3NCH2CH2NH3) 3[(VO)12O4 {B8O17(OH) 4}2{Na(H2O)}2]·(H 3O)2(H2O)6.5 - Details

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Abstract：

A　novel　one-dimensional　polyoxovanadium　borate　(H3NCH　2CH2NH3)3[(VO)12O　4{B8O17(OH)4}2{Na(H　2O)}2]·(H3O)2(H　2O)6.5　(1)　has　been　synthesized　by　the　hydrothermal　method　and　the　structure　determined　by　X-ray　crystallography.　The　structure　consists　of　a　continuous　contorted　V12　ring,　constructed　from　edge-sharing　VO5　square　pyramids.　Two　{B8O17(OH)　4}14-　polyborate　chains　fill　in　the　cavities　formed　by　the　V12　ring.　The　[(VO)12O4{B8O　17(OH)4}2]12-　clusters　are　connected　by　unusual　binuclear　Na+　units　into　1D　chains.　The　binuclear　Na　+　units　are　formed　by　two　neighboring　sodium　atoms　sharing　two　μ2-O　from　B-O-B.　Each　sodium　atom　is　in　a　distorted　octahedral　geometry.　Other　characterizations　are　also　described　by　elemental　analysis,　thermal　analysis　and　IR,　EPR　spectra.　©　2004　Elsevier　B.V.　All　rights　reserved.

Keyword：

Atoms Boron compounds Crystal structure Electron spin resonance spectroscopy Hydrothermal synthesis Sodium Thermoanalysis X ray crystallography

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[ 1 ] [Cao, Yanning]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's R.
[ 2 ] [Zhang, Hanhui]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's R.
[ 3 ] [Zhang, Hanhui]State Key Lab. of Struct. Chemistry, Fujian Inst. Res. Struct. of Matter, Chinese Acad. Sci., Fuzhou, F.
[ 4 ] [Huang, Changcang]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's R.
[ 5 ] [Chen, Yiping]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's R.
[ 6 ] [Sun, Ruiqing]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's R.
[ 7 ] [Guo, Wenjun]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's R.

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Source ：

Journal of Molecular Structure

ISSN： 0022-2860

Year： 2005

Issue： 1-3

Volume： 733

Page： 211-216

1 . 4 4

JCR@2005

4 . 0 0 0

JCR@2023

JCR Journal Grade：3

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SCOPUS Cited Count： 27

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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