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author:

Liu, Huiyong (Liu, Huiyong.) [1] | Wang, Wenji (Wang, Wenji.) [2] | Li, Ronghua (Li, Ronghua.) [3] | Cai, Zengliang (Cai, Zengliang.) [4]

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EI

Abstract:

Li0.2375+xLa0.5875-xSrxTiO3-LaPO4fast ionic conductor was synthesized by high temperature solid state reaction. A. C. impedance measurements show that the system has higher conductivity in low doping content of Sr2+, but the conductivity goes down from 5.78×10-5to 3.11×10-7S·cm-1with increasing the content of Sr2+. The activation energy is about 20 kJ·mol-1in the temperature range of 25-400°C. X-ray powder diffraction shows that the doping Sr2+would not affect the structure of compositions in the system. The main phase is Li0.2375+xLa0.5875-xSrxTiO3perovskite solid solution, LaPO4as a second phase can also be found. With increasing the content of Sr2+(x>0.05), another phase SrTiO3appears. IR measurement also indicates that the structure of compositions in the system would not be affected by Sr2+doping. The decomposition voltage of Li0.2375+xLa0.5875-xSrxTiO3-LaPO4remain unchanged (1.5 V).

Keyword:

Electric conductivity of solids Inorganic chemicals Ionic conduction in solids Perovskite Rare earth elements Structure (composition) X ray diffraction analysis

Community:

  • [ 1 ] [Liu, Huiyong]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China
  • [ 2 ] [Wang, Wenji]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China
  • [ 3 ] [Li, Ronghua]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China
  • [ 4 ] [Cai, Zengliang]Dept. of Chem., Fuzhou Univ., Fuzhou 350002, China

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Source :

Journal of Rare Earths

ISSN: 1002-0721

Year: 2004

Issue: 2

Volume: 22

Page: 223-226

0 . 4 9 3

JCR@2004

5 . 2 0 0

JCR@2023

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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