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author:

Liu, Yineng (Liu, Yineng.) [1] | Xu, Jinying (Xu, Jinying.) [2] (Scholars:徐金英)

Indexed by:

EI Scopus

Abstract:

We have found that strong superchiral fields created by surface plasmon resonance exist in hot spots of nonchiral plasmonic structure, which showed a chiral density greater than that of circularly polarized light by hundreds of times. We have demonstrated a direct correlation between the strong chirality of the local field and the giant CD response at the plasmon resonance bands induced by chiral molecules in the hot spots. Our results reveal that the wavelengthdependent superchiral fields in the hot spots can play a crucial role in the determination of the plasmonic CD effect. This finding is in contrast to the currently accepted physical model in which the electromagnetic field intensity in hot spots is a key factor to determine the peak intensity of the plasmonic CD spectrum. Some related experimental phenomena have been explained by using our theoretical analysis. © OSA 2016.

Keyword:

Dichroism Electromagnetic fields Molecules Plasmonics Stereochemistry

Community:

  • [ 1 ] [Liu, Yineng]Department of Electronic Science, Xiamen University, Xiamen; 361005, China
  • [ 2 ] [Xu, Jinying]Department of Electronic Science, Xiamen University, Xiamen; 361005, China
  • [ 3 ] [Xu, Jinying]Department of Physics, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • [liu, yineng]department of electronic science, xiamen university, xiamen; 361005, china

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Source :

Year: 2016

Language: English

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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