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author:

Chen, X.-H. (Chen, X.-H..) [1] | Liu, S.-X. (Liu, S.-X..) [2]

Indexed by:

Scopus PKU CSCD

Abstract:

The title nickel complex with 1,2-disalicyloylhydrazine, [Ni(en) 3]2+·H2dsh2-, has been synthesized. It crystallizes in orthorhombic, space group P212 121 with a = 10.5094(4), b = 12.5003(8), c = 17.487(1) Å, V = 2297.2(2) Å3, Z = 4, Mr = 509.26, Dc = 1.472 g/cm3, μ = 0.889 mm-1, F(000) = 1080, R = 0.0327 and wR = 0.0375. Six nitrogen atoms of three ethylenediamine ligands in the cation coordinate to the Ni(II) ion, forming a distorted octahedron. The bond distances of Ni(II)-N(en) range from 2.110(3) to 2.151(2) Å. The neighboring molecules of the title complex are linked by intermolecular N-H..O hydrogen bonds between [Ni(en)3]2+ dications and H2dsh2- dianions, forming a two-dimensional network.

Keyword:

1,2-disalicyloylhydrazine; Crystal structure; Ethylenediamine; Nickel complex

Community:

  • [ 1 ] [Chen, X.-H.]Central Laboratory, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • 陈小华

    [Chen, X.-H.]Central Laboratory, Fuzhou University, Fuzhou 350002, China

Email:

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Source :

Jiegou Huaxue

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2004

Issue: 6

Volume: 23

Page: 587-590

0 . 7 3 4

JCR@2004

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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