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author:

Li, H.-H. (Li, H.-H..) [1] | Chen, Z.-R. (Chen, Z.-R..) [2] | Huang, C.-C. (Huang, C.-C..) [3] | Ren, Y.-G. (Ren, Y.-G..) [4] | Chen, Q.-H. (Chen, Q.-H..) [5]

Indexed by:

Scopus PKU CSCD

Abstract:

A novel coordination polymer {(C12H14N 2)[Ag2I4]}n ([C12H 14N2]2+ = N,N′-1,2-ethyl-dipyridinium (EDP)) was synthesized by the reaction of AgI with EDP (pH = 6.5) at room temperature and structurally characterized by X-ray single-crystal diffraction analysis. The title compound crystallizes in monoclinic, space group P2 1/n with a = 7.278(2), b = 23.658(2), c = 12.038(2) Å, β = 98.25°, V = 2051.3(7) Å3, Z = 4, Dc = 2.945 g/cm3, F(000) = 1624, C12H14Ag 2[4N2, Mr = 909.59, μ(MoKα) = 7.922 mm-1, the final R = 0.0321 and wR = 0.0615 for 3079 observed reflections with I > 2σ(I). The title compound consists of cations ([C12H14N2]2+) and anion chain (Ag2I42-) which are combined by static attracting forces in the crystal.

Keyword:

Coordination polymers; Iodide; Quaternary ammonium; Template synthesis

Community:

  • [ 1 ] [Li, H.-H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 2 ] [Chen, Z.-R.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 3 ] [Huang, C.-C.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 4 ] [Ren, Y.-G.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 5 ] [Chen, Q.-H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address:

  • [Chen, Z.-R.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2004

Issue: 3

Volume: 23

Page: 288-291

0 . 7 3 4

JCR@2004

5 . 9 0 0

JCR@2023

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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