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Abstract:
A novel coordination polymer {(C12H14N 2)[Ag2I4]}n ([C12H 14N2]2+ = N,N′-1,2-ethyl-dipyridinium (EDP)) was synthesized by the reaction of AgI with EDP (pH = 6.5) at room temperature and structurally characterized by X-ray single-crystal diffraction analysis. The title compound crystallizes in monoclinic, space group P2 1/n with a = 7.278(2), b = 23.658(2), c = 12.038(2) Å, β = 98.25°, V = 2051.3(7) Å3, Z = 4, Dc = 2.945 g/cm3, F(000) = 1624, C12H14Ag 2[4N2, Mr = 909.59, μ(MoKα) = 7.922 mm-1, the final R = 0.0321 and wR = 0.0615 for 3079 observed reflections with I > 2σ(I). The title compound consists of cations ([C12H14N2]2+) and anion chain (Ag2I42-) which are combined by static attracting forces in the crystal.
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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2004
Issue: 3
Volume: 23
Page: 288-291
0 . 7 3 4
JCR@2004
5 . 9 0 0
JCR@2023
JCR Journal Grade:3
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 4
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