Synthesis and crystal structure of the heteropolymate compound Na3H2[Ce-3(H2O)(18)Bi2W22O76]center dot 23H(2)O - Details

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Abstract：

A　Bi(III)　contained　heteropolymate　compound　Na　3　H　2　[Ce　3　(H　2　O)　18　Bi　2　W　22　O　76　]　·23H　2　O　1　has　been　synthesized.　It　crystallizes　in　the　triclinic　system,　space　group　P1　with　a　=　14.370(3),　b　=　17.113(3),　c　=　24.764(5)　Å,　α　=　74.33(3),　β　=　77.20(3),　γ　=　65.29(3)°,　V　=　5285.3(18)　Å　3　,　Z　=　2,　M　r　=　6908.66,　D　c　=　4.341　g/cm　3　,　F(000)　=　6042,　μ(MoKα)　=　28.543　mm　-1　,　R　=　0.0604　and　wR　=　0.1659　for　15788　reflections　with　I　>　2σ(I).　The　structure　analysis　revealed　that　in　the　anionic　framework　of　the　title　compound　the　[Bi　2　W　22　O　76　]　14-　anions　are　connected　by　Ce　3+　and　Na　+　cations　into　a　three　dimensional　network.

Keyword：

Bismuth(III) heteropolymate; Crystal structure; Polyoxometalate

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[ 1 ] [Wang, Y.-J.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 2 ] [Wang, Y.-J.]State Key Lab. of Struct. Chemistry, Fuzhou 350002, China
[ 3 ] [Yu, X.-H.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 4 ] [Zhang, H.-H.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 5 ] [Zhang, H.-H.]State Key Lab. of Struct. Chemistry, Fuzhou 350002, China
[ 6 ] [Sun, Q.-Z.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 7 ] [Huang, C.-C.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 8 ] [Huang, C.-C.]State Key Lab. of Struct. Chemistry, Fuzhou 350002, China
[ 9 ] [Sun, R.-Q.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

[Zhang, H.-H.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Email：

hhzhang@fzu.edu.cn

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Source ：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2004

Issue： 8

Volume： 23

Page： 902-907

0 . 7 3 4

JCR@2004

5 . 9 0 0

JCR@2023

JCR Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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