Structure of ethanol coordinated 1,8,15,22-tetra-(2′,2′, 4′-trimethyl-3′-pentoxy)phthalocyaninatocobalt - Details

author：

Wang, J.-D. (Wang, J.-D..) ^[1] (Scholars：王俊东) | Huang, J.-L. (Huang, J.-L..) ^[2] | Xu, X.-Z. (Xu, X.-Z..) ^[3] | Cai, J.-W. (Cai, J.-W..) ^[4] | Chen, N.-S. (Chen, N.-S..) ^[5]

Indexed by：

Scopus PKU CSCD

Abstract：

Crystal　structure　of　ethanol　coordinated　1,8,15,22-tetra(2′,2′,　4′-trimethyl-3-pentoxy)　phthalocyaninatocobalt　(C64H　80N8O4Co　2C2H5OH,　M　r　=　1176.43)　was　determined　by　X-ray　diffraction　methods.　The　crystal　is　of　monoclinic,　space　group　P21/c　with　a　=　16.4294(4),　b　=　8.0560(2),　c　=　24.3654(7)　Å,　β　=　98.3680(8)°,　Z　=　2,　V　=　3190.6(1)　Å3,　Dc　=　1.225　g/cm3,　F(000)　=　1262,　μ(MoKα)　=　0.326　mm-1,　the　final　R　=　0.0865　and　wR　=　0.2737　for　4787　observed　reflections　with　I　≥　2σ(I).　The　bulky　branched　alkyloxy　substituents　lead　to　a　one　structural　isomer　and　space　the　phthalocyanine　molecules　where　two　ethanol　molecules　coordinate　to　the　cobalt　atom　from　two　sides　of　each　molecule.

Keyword：

Crystal structure; Phthalocyanine; Substituted phthalocyanine

Community：

[ 1 ] [Wang, J.-D.]Department of Chemistry, Fuzhou University, State Key Lab. of Struct. Chemistry, Fuzhou 350002, China
[ 2 ] [Huang, J.-L.]Department of Chemistry, Fuzhou University, State Key Lab. of Struct. Chemistry, Fuzhou 350002, China
[ 3 ] [Xu, X.-Z.]Department of Chemistry, Fuzhou University, State Key Lab. of Struct. Chemistry, Fuzhou 350002, China
[ 4 ] [Cai, J.-W.]Department of Chemistry, Fuzhou University, State Key Lab. of Struct. Chemistry, Fuzhou 350002, China
[ 5 ] [Chen, N.-S.]Department of Chemistry, Fuzhou University, State Key Lab. of Struct. Chemistry, Fuzhou 350002, China

Reprint 's Address：

黄金陵
[Huang, J.-L.]Department of Chemistry, Fuzhou University, State Key Lab. of Struct. Chemistry, Fuzhou 350002, China

Email：

hjl@fzu.edu.cn

Show more details

Related Keywords：

Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2004

Issue： 5

Volume： 23

Page： 516-519

0 . 7 3 4

JCR@2004

5 . 9 0 0

JCR@2023

JCR Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 3

Affiliated Colleges：

化学学院本学院/部未明确归属的数据

Get Fulltext

Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to