A mercury iodide adduct with 1,1-bis(diphenylphosphino)ferrocene - Synthesis, crystal structure, and nonlinear refractive properties - Details

author：

Niu, Y.-Y. (Niu, Y.-Y..) ^[1] | Song, Y.-L. (Song, Y.-L..) ^[2] | Liu, S.-X. (Liu, S.-X..) ^[3] | Xin, X.-Q. (Xin, X.-Q..) ^[4]

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Scopus

Abstract：

A　new　mercury　iodide　complex　of　dppf,　[HgI2(dppf)]　(adduct　1,　dppf　=　1,1-bis(diphenylphosphino)ferrocene)　was　prepared　and　characterized.　Single　crystal　X-ray　diffraction　analysis　established　that　the　compound　crystallizes　in　the　monoclinic　system,　space　group　C2c,　with　a　=　34.992(3),　b　=　10.236(5),　c　=　18.765(4)　Å,　β　=　99.410(2)°,　Z　=　8,　V　=　6631.2(9)　Å3.　The　coordination　about　the　mercury　atom　is　tetrahedral　with　two　equivalent　Hg-I　and　Hg-P　bonds.　Dppf　functions　as　a　chelating　ligand.　The　nonlinear　optical　(NLO)　properties　were　studied　with　an　8ns-pulsed　laser　at　532　nm.　Its　optical　responses　to　the　incident　light　exhibit　weak　optical　absorptive　and　strong　refractive　effects,　with　n2　=　6.86　×　10-18　m2　·　W-1　in　a　2.48　×　10-4　mol　·　dm-3　DMF　solution.

Keyword：

Crystal structure; Mercury; Nonlinear optical properties

Community：

[ 1 ] [Niu, Y.-Y.]Coordination Chemistry Institute, Nanjing University, Nanjing, China
[ 2 ] [Song, Y.-L.]Physical Department, Harbin Institute of Technology, Harbin, China
[ 3 ] [Liu, S.-X.]Central Laboratory of Fuzhou University, Fuzhou, China
[ 4 ] [Xin, X.-Q.]Coordination Chemistry Institute, Nanjing University, Nanjing, China
[ 5 ] [Xin, X.-Q.]Coordination Chemistry Institute, Nanjing University, Nanjing, Jiangsu, 210093, China

Reprint 's Address：

[Xin, X.-Q.]Coordination Chemistry Institute, Nanjing University, Nanjing, Jiangsu 210093, China

Email：

xxin@netra.nju.edu.cn

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Source ：

Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2002

Issue： 1

Volume： 628

Page： 179-182

1 . 1 9 6

JCR@2002

1 . 1 0 0

JCR@2023

JCR Journal Grade：3

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