A study on the oxidative carbonylation of aniline - Details

author：

Wang, W. (Wang, W..) ^[1] (Scholars：王文峰) | Zhang, F. (Zhang, F..) ^[2] | Xu, P. (Xu, P..) ^[3]

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Abstract：

The　oxidative　carbonylation　of　aniline　to　catbamate　over　Pd-based　catalyst　was　studied　by　using　NaI　and　absolute　ethanol　as　the　promoter　and　solvent,　respectively.　The　optimum　process　conditions　for　this　reaction　were　investigated.　At　170　°C,　after　2　h　of　reaction,　the　Pd/C　catalyst　exhibited　high　activity　(97.49%)　and　high　selectivity　(85.26%).　The　promoter　role　of　NaI　was　discussed,　and　a　mechanism　for　the　title　reaction　was　proposed.

Keyword：

Aniline; Carbamate; Oxidative carbonylation; Pd-based catalyst

Community：

[ 1 ] [Wang, W.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Zhang, F.]Department of Chemistry, Xiamen University, Xiamen, Fujian 361005, China
[ 3 ] [Xu, P.]Department of Chemistry, Xiamen University, Xiamen, Fujian 361005, China

Reprint 's Address：

王文峰
[Wang, W.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

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Source ：

Journal of Natural Gas Chemistry

ISSN： 1003-9953

Year： 2000

Issue： 3

Volume： 9

Page： 243-248,262

2 . 3 9 8

JCR@2014

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 2

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