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Abstract：
Electrochemical behaviors for a series of trinuclear molybdenum cluster compounds [Mo3OCl6 (O2CR)3]- in acetonitrile and dimethylformide solvents were studied with cyclic voltammetry in this paper. Two redox peaks were assigned. The effect of changing R radical of carboxyl on the redox characteristics of these cluster compounds was discussed preliminarily. In addition, their thermal stability and the thermolytic behavior in nitrogen atmosphere were investigated by DTA-TG method. The effect of changing R radical on the thermal stability of the cluster compounds was discussed. Their possible thermolytic mechanism was also offered.
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Jiegou Huaxue
ISSN： 0254-5861
CN： 35-1112/TQ
Year： 1996
Issue： 3
Volume： 15
Page： X4-192
5 . 9 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
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ESI Highly Cited Papers on the List： 0 Unfold All
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30 Days PV： 1
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