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Abstract:
The title complex was prepared and its crystal structure was determined. The crystal is space group P 1̄ with parameters; a = 1. 191 1(2) nm, b = 1.532 2(2) nm, c = 1.049 2(2) nm, α = 108. 98(1)°, β = 107. 04(1)°, γ = 70.25(1)°, Z = 2, T = 296 K and the final R = 0. 054 1 for 3 998 observed reflections. The Cu atom is five-coordinated with a distorted trigonal bipyramid. Four nitrogen atoms from two 2,2′-dipyridyl ligands and one carboxyl oxygen atom from benzilate form a distorted trigonal plane, while the other two nitrogen atoms from the two 2,2′-dipyridyl ligands occupy the two axial positions. The assignment in IR spectrum is discussed.
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CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN: 0251-0790
Year: 1996
Issue: 2
Volume: 17
Page: x1-172
0 . 7 0 0
JCR@2023
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