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author:

Liu, S.-X. (Liu, S.-X..) [1] | Wang, X. (Wang, X..) [2]

Indexed by:

Scopus PKU CSCD

Abstract:

The title complex was prepared and its crystal structure was determined. The crystal is space group P 1̄ with parameters; a = 1. 191 1(2) nm, b = 1.532 2(2) nm, c = 1.049 2(2) nm, α = 108. 98(1)°, β = 107. 04(1)°, γ = 70.25(1)°, Z = 2, T = 296 K and the final R = 0. 054 1 for 3 998 observed reflections. The Cu atom is five-coordinated with a distorted trigonal bipyramid. Four nitrogen atoms from two 2,2′-dipyridyl ligands and one carboxyl oxygen atom from benzilate form a distorted trigonal plane, while the other two nitrogen atoms from the two 2,2′-dipyridyl ligands occupy the two axial positions. The assignment in IR spectrum is discussed.

Keyword:

Benzilate; Copper complex; Crystal structure; IR spectrum

Community:

  • [ 1 ] [Liu, S.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Wang, X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Liu, S.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

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Source :

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE

ISSN: 0251-0790

Year: 1996

Issue: 2

Volume: 17

Page: x1-172

0 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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