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author:

Yang, Z.-F. (Yang, Z.-F..) [1] | Li, L.-Y. (Li, L.-Y..) [2] | Hsieh, C.-T. (Hsieh, C.-T..) [3] | Juang, R.-S. (Juang, R.-S..) [4] | Gandomi, Y.A. (Gandomi, Y.A..) [5]

Indexed by:

Scopus

Abstract:

Liquid-phase adsorption of Cu2+ ions onto magnetic Fe3O4@graphene oxide (GO) composites, prepared by a co-precipitation approach, has been investigated. This synthesis method is capable of depositing highly crystalline Fe3O4 nanoparticles onto GO sheets. The adsorption temperature and the weight ratio of Fe3O4 nanoparticles to GO sheets are found to be crucial factors affecting the adsorption performance. The pH value of the aqueous solution has a strong influence on the adsorption capacity of Cu2+ ions. The Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) adsorption models were adopted to fit the adsorption isotherms. The deposition of magnetite enhances the equilibrium rate constant (Langmuir model) and the adsorption energy (D-R model). The analysis of thermodynamic parameters reveals that the adsorption of Cu2+ ions is a favorable and spontaneous process. However, a moderate density of magnetite onto GO substrate is essential for the design of Fe3O4@GO adsorbents for efficient removal of metal ions from an aqueous solution. © 2018 Elsevier B.V.

Keyword:

Adsorption capacity; Composite adsorbent; Graphene oxide; Liquid-phase adsorption; Magnetite

Community:

  • [ 1 ] [Yang, Z.-F.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Li, L.-Y.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Hsieh, C.-T.]Department of Chemical Engineering and Materials Science, Yuan Ze University, Taoyuan, 32003, Taiwan
  • [ 4 ] [Hsieh, C.-T.]Department of Mechanical, Aerospace and Biomedical Engineering, University of Tennessee, Knoxville, TN 37996, United States
  • [ 5 ] [Juang, R.-S.]Department of Chemical and Materials Engineering, Chang Gung University, Guishan, Taoyuan 33302, Taiwan
  • [ 6 ] [Juang, R.-S.]Division of Nephrology, Department of Internal Medicine, Chang Gung Memorial Hospital, Linkou, Taiwan
  • [ 7 ] [Juang, R.-S.]Department of Chemical and Materials Engineering, Chang Gung University, Guishan, Taoyuan, 33302, Taiwan
  • [ 8 ] [Gandomi, Y.A.]Department of Mechanical, Aerospace and Biomedical Engineering, University of Tennessee, Knoxville, TN 37996, United States

Reprint 's Address:

  • [Li, L.-Y.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Materials Chemistry and Physics

ISSN: 0254-0584

Year: 2018

Volume: 219

Page: 30-39

2 . 7 8 1

JCR@2018

4 . 3 0 0

JCR@2023

ESI HC Threshold:284

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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