N-Heterocyclic Carbene (NHC) Organocatalytic One-Pot Reaction for the Enantioselective Synthesis of Fluoromethylated Chromenones - Details

author：

Wang, B. (Wang, B..) ^[1] | Huang, L. (Huang, L..) ^[2] | Hou, Y. (Hou, Y..) ^[3] | Lan, S. (Lan, S..) ^[4] | Cheng, J. (Cheng, J..) ^[5]

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Abstract：

An　efficient　carbene　organocatalyzed　route　to　enantioenriched　chromenones,　bearing　one　tri-　or　difluoromethylated　stereogenic　center　in　the　β　position　of　the　carbonyl　group,　from　o-allyloxybenzaldehydes　is　described.　The　one-pot　transition-metal-free　transformation　exhibits　a　broad　substrate　scope　and　excellent　enantioselectivity.　©　2018　American　Chemical　Society.

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[ 1 ] [Wang, B.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Huang, L.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 3 ] [Hou, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Lan, S.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 5 ] [Cheng, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 6 ] [Cheng, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

Reprint 's Address：

[Cheng, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

jjcheng@fzu.edu.cn

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Source ：

Organic Letters

ISSN： 1523-7060

Year： 2018

Issue： 19

Volume： 20

Page： 6012-6016

6 . 5 5 5

JCR@2018

4 . 9 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：1

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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