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author:

Zhang, B. (Zhang, B..) [1] | Wu, K. (Wu, K..) [2] | Peng, K. (Peng, K..) [3]

Indexed by:

Scopus

Abstract:

Nd2-xInxCe2O7 (x = 0, 0.05, 0.10, 0.15 and 0.20) powders are successfully synthesized by citric acid-nitrate sol-gel combustion method. The influence of In doping on the phase structure, morphology, and electrical conduction behavior of neodymium cerium is characterized by X-ray diffraction, Raman spectroscopy, scanning electron microscopy and electrochemical impedance spectroscopy. All Nd2-xInxCe2O7 ceramics are found to possess a fluorite-type structure. Moreover, Nd1.85In0.15Ce2O7 pellets keep sufficiently excellent chemical stability under different atmospheres containing CO2, water and wet hydrogen. Highly dense ceramics with increasing grain size are obtained by sintering at reduced temperature resulting from indium incorporation promotes sinterability of Nd2-xInxCe2O7. The Nd1.85In0.15Ce2O7 pellet promises the highest total conductivities of 0.75 × 10−2 and 2.07 × 10−2 S cm-1 at 700 °C in dry air and wet 5% H2-Ar conditions, respectively. Furthermore, an anode-supported single cell with dense Nd1.85In0.15Ce2O7 electrolyte film is successfully assembled and evaluated. The maximum power density of the cell reaches 743 mW cm-2 at 700 °C. The results indicate that In-doped Nd2Ce2O7 is a promising candidate as a proton-conducting electrolyte for intermediate-temperature solid oxide fuel cells. © 2018 Elsevier B.V.

Keyword:

Chemical stability; Conductivity; Electrolyte; Neodymium cerium; Solid oxide fuel cells

Community:

  • [ 1 ] [Zhang, B.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 2 ] [Wu, K.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 3 ] [Peng, K.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350116, China

Reprint 's Address:

  • [Peng, K.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2018

Volume: 399

Page: 157-165

7 . 4 6 7

JCR@2018

8 . 1 0 0

JCR@2023

ESI HC Threshold:284

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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