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author:

Lin, X. (Lin, X..) [1] | Chen, H. (Chen, H..) [2] | Hu, Z. (Hu, Z..) [3] | Hou, Y. (Hou, Y..) [4] | Dai, W. (Dai, W..) [5]

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Scopus

Abstract:

TiO2 photocatalysis has been studied widely in environment protection and energy generation applications. But, the intrinsic absence of visible light response and the high recombination rate of photo-generated charge carriers significantly limited the efficiency of photocatalysis with TiO2 materials. Herein, a facile approach was constructed to develop visible-light-induced TiO2 photocatalysis by co-modification with Eu and Au nanoparticles. The synthesized Au/Eu-TiO2 material was characterized by XRD, SEM, TEM, DRS, XPS, and N2 adsorption measurements. Visible light catalytic performance of the Au/Eu-TiO2 catalyst was evaluated by using the photodegradation of RhB as a model reaction. It was shown that this Au/Eu-TiO2 exhibited a better photocatalytic activity than the single Au modified TiO2 (Au/TiO2) or the single Eu modified TiO2 catalyst (Eu/TiO2), and also exhibited a good reusability for the targeted reaction. This remarkably improved performance of Au/Eu-TiO2 could be attributed to the synergetic effect of Eu and Au co-decoration, which not only enhanced visible light absorption but also promoted charge carriers transfers as evidenced by DRS, XPS and transient photocurrent spectra. Moreover, a possible reaction mechanism for the Au/Eu-TiO2 photocatalysis was proposed. © 2018 Elsevier Masson SAS

Keyword:

Co-modification; Electron transfer; Synergetic effect; TiO2; Visible light response

Community:

  • [ 1 ] [Lin, X.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 2 ] [Lin, X.]College of Chemistry & Materials Science, Longyan University, Longyan, Fujian 364012, China
  • [ 3 ] [Chen, H.]College of Chemistry & Materials Science, Longyan University, Longyan, Fujian 364012, China
  • [ 4 ] [Hu, Z.]College of Chemistry & Materials Science, Longyan University, Longyan, Fujian 364012, China
  • [ 5 ] [Hou, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 6 ] [Dai, W.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 7 ] [Dai, W.]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province, Fuzhou, 350002, China

Reprint 's Address:

  • [Dai, W.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou UniversityChina

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Source :

Solid State Sciences

ISSN: 1293-2558

Year: 2018

Volume: 83

Page: 181-187

2 . 1 5 5

JCR@2018

3 . 4 0 0

JCR@2023

ESI HC Threshold:158

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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