Rhodium(II)-Catalyzed C−H Bond Carboxylation of Heteroarenes with CO2 - Details

author：

Huang, R. (Huang, R..) ^[1] | Li, S. (Li, S..) ^[2] | Fu, L. (Fu, L..) ^[3] | Li, G. (Li, G..) ^[4]

Indexed by：

Scopus

Abstract：

A　method　of　RhII-catalyzed　C−H　carboxylation　of　2-(imidazo[1,2-a]pyridin-2-yl)phenols　via　CO2　fixation　under　redox-neutral　conditions　was　reported,　providing　an　access　to　a　range　of　coumarin　derivatives.　A　suitable　diphosphine　ligand　was　crucial　for　this　reaction.　This　reaction　could　be　performed　under　relatively　lower　temperature　or　in　a　shorter　time　than　the　alternative　base-promoted　protocol.　©　2018　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

carbon dioxide fixation; carboxylation; C−H activation; redox-neutral; rhodium

Community：

[ 1 ] [Huang, R.]College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Huang, R.]Key Laboratory of Coal to Ethylene Glycol, and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 3 ] [Li, S.]Key Laboratory of Coal to Ethylene Glycol, and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 4 ] [Fu, L.]Key Laboratory of Coal to Ethylene Glycol, and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 5 ] [Li, G.]Key Laboratory of Coal to Ethylene Glycol, and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Li, G.]Key Laboratory of Coal to Ethylene Glycol, and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

gangli@fjirsm.ac.cn

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Source ：

Asian Journal of Organic Chemistry

ISSN： 2193-5807

Year： 2018

Issue： 7

Volume： 7

Page： 1376-1379

2 . 4 9 6

JCR@2018

2 . 8 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 18

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 3

Affiliated Colleges：

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